eprintid: 3097
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/30/97
datestamp: 2023-11-09 15:51:21
lastmod: 2023-11-09 15:51:21
status_changed: 2023-11-09 15:44:58
type: article
metadata_visibility: show
creators_name: Nasrifar, K.
creators_name: Moshfeghian, M.
title: Multiphase equilibria of waxy systems with predictive equations of state and a solid solution model
ispublished: pub
keywords: Activity coefficient model; Adjustable parameters; Correction factors; Equation of state; Equilibrium calculations; Gas condensate mixture; High pressure; Liquid phasis; Multiphase equilibria; Predictive equations; Pressure and temperature; Real systems; Solid-liquid; Solid-liquid-vapor equilibria; Solid-phase; Solid-vapor; Thermodynamic model; Vapor-liquid, Equations of state of liquids; Gas condensates; Liquids; Methane; Phase boundaries; Vapors; Waxes, Solid solutions
note: cited By 12
abstract: A thermodynamic model is developed to predict the vapor-liquid, solid-liquid, solid-vapor and solid-liquid-vapor equilibria of systems containing methane with waxy components. The model takes the advantages of equations of state to describe the vapor and liquid phases. The solid phase is described by Coutinho's activity coefficient model, i.e., the solid phase is assumed to be orthorhombic solid solution. Impact of pressure on the solid phase is included by coupling solid-liquid Clapeyron relationship with Poynting correction factor. While no adjustable parameter is used, the model satisfactorily predicts the phase boundaries of the synthetic and real systems resembling gas condensate mixtures for wide ranges of pressure and temperature. © 2011 Elsevier B.V.
date: 2012
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-83655201125&doi=10.1016%2fj.fluid.2011.10.019&partnerID=40&md5=87aec0c45e119a5930453377ec337477
id_number: 10.1016/j.fluid.2011.10.019
full_text_status: none
publication: Fluid Phase Equilibria
volume: 314
pagerange: 60-68
refereed: TRUE
issn: 03783812
citation:   Nasrifar, K. and Moshfeghian, M.  (2012) Multiphase equilibria of waxy systems with predictive equations of state and a solid solution model.  Fluid Phase Equilibria, 314.  pp. 60-68.  ISSN 03783812