eprintid: 3018
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/30/18
datestamp: 2023-11-09 15:51:16
lastmod: 2023-11-09 15:51:16
status_changed: 2023-11-09 15:44:48
type: article
metadata_visibility: show
creators_name: Rafiq, S.
creators_name: Man, Z.
creators_name: Maulud, A.
creators_name: Muhammad, N.
creators_name: Maitra, S.
title: Separation of CO 2 from CH 4 using polysulfone/ polyimide silica nanocomposite membranes
ispublished: pub
keywords: Asymmetric membranes; Fourier transform infrared (FTIR) spectroscopies; Gas separations; Hybrid membrane; Ideal gas; Mixed gas; Mixed matrix membranes; Permselectivities; Phase inversion techniques; Silica content; Silica nanocomposites; Silica nanoparticles, Carbon dioxide; Fourier transform infrared spectroscopy; Loading; Polyimides; Polysulfones; Scanning electron microscopy; Separation; Silica; Thermogravimetric analysis; X ray diffraction, Gas permeable membranes
note: cited By 102
abstract: Mixed matrix membranes (MMMs) were developed by incorporating inorganic silica nanoparticles into blends of polysulfone/polyimide (PSF/PI) asymmetric membranes for gas separation using phase inversion technique. The membranes were characterized by using scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA). SEM results show different morphologies of surfaces and cross-sections of the membrane where agglomeration is observed at 20.1 wt. silica loading. TGA analysis indicates good thermal stability of the hybrid membranes. Permeation results show that CO 2 permeance increased with the introduction of 5.2 wt. silica contents (73.7 ± 0.2 GPU) in PSF/PI-20 blend and it increased with the increase in silica contents. With 15.2 wt. silica contents, the highest permselectivity of αCO 2/CH 4 = 61.0 ± 0.3-60.2 ± 0.4 is observed for treated membrane at 2-10 bar. The selectivity using mixed gas test at various CO 2/CH 4 compositions shows consistent results with the ideal gas selectivity. © 2012 Elsevier B.V. All rights reserved.
date: 2012
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84858741345&doi=10.1016%2fj.seppur.2012.02.031&partnerID=40&md5=94404d7ac3afa91f31ee2cfbe6ae29e5
id_number: 10.1016/j.seppur.2012.02.031
full_text_status: none
publication: Separation and Purification Technology
volume: 90
pagerange: 162-172
refereed: TRUE
issn: 13835866
citation:   Rafiq, S. and Man, Z. and Maulud, A. and Muhammad, N. and Maitra, S.  (2012) Separation of CO 2 from CH 4 using polysulfone/ polyimide silica nanocomposite membranes.  Separation and Purification Technology, 90.  pp. 162-172.  ISSN 13835866