eprintid: 2684
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/26/84
datestamp: 2023-11-09 15:50:55
lastmod: 2023-11-09 15:50:55
status_changed: 2023-11-09 15:44:03
type: article
metadata_visibility: show
creators_name: Kurnia, K.A.
creators_name: Mutalib, M.I.A.
creators_name: Man, Z.
creators_name: Bustam, M.A.
title: Density and surface tension of ionic liquids H 2N-C 2mimPF 6 and H 2N-C 3mimPF 6
ispublished: pub
keywords: Boiling temperature; Critical temperatures; Experimental values; Functionalized ionic liquids; Hexafluorophosphates; Lattice energies; Molar enthalpy; Molecular volume; Parachor methods; Standard molar entropy; Thermal expansion coefficients, Physical properties; Surface tension, Ionic liquids
note: cited By 11
abstract: Two amino functionalized ionic liquids 1-(2-aminoethyl)-3-methylimidazolium hexafluorophosphate, H 2N-C 2mimPF 6, and 1-(3-aminopropyl)-3-methylimidazolium hexafluorophosphate, H 2N-C 3mimPF 6, were synthesized and characterized. The density and surface tension of these ionic liquids were measured from (293.15 to 343.15) K. Their values decreased with increasing temperature. The physical properties such as coefficient of thermal expansion, molecular volume, standard molar entropy, lattice energy, and molar enthalpy of vaporization were estimated using experimental data. The critical temperature of the ionic liquids was estimated using Eötvos equations. The values were then used to estimate the boiling temperature of the ionic liquids according to methods of Rebelo. The interstice model was used to predict the thermal expansion coefficient of the ionic liquids, α, and the result was in very good agreement with the experimental value. In addition, the parachor method was used to predict the physical properties of the ionic liquids H 2N-C nmimPF 6 (n = 4, 5, 6). © 2012 American Chemical Society.
date: 2012
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84868681863&doi=10.1021%2fje300288a&partnerID=40&md5=1c63751a71512fbf008fd1e4f726e366
id_number: 10.1021/je300288a
full_text_status: none
publication: Journal of Chemical and Engineering Data
volume: 57
number: 11
pagerange: 2923-2927
refereed: TRUE
issn: 00219568
citation:   Kurnia, K.A. and Mutalib, M.I.A. and Man, Z. and Bustam, M.A.  (2012) Density and surface tension of ionic liquids H 2N-C 2mimPF 6 and H 2N-C 3mimPF 6.  Journal of Chemical and Engineering Data, 57 (11).  pp. 2923-2927.  ISSN 00219568