eprintid: 2573
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/25/73
datestamp: 2023-11-09 15:50:48
lastmod: 2023-11-09 15:50:48
status_changed: 2023-11-09 15:43:49
type: conference_item
metadata_visibility: show
creators_name: Shaharun, M.S.
creators_name: Mustafa, A.K.
creators_name: Taha, M.F.
title: Nanofiltration of rhodium tris(triphenylphosphine) catalyst in ethyl acetate solution
ispublished: pub
note: cited By 5; Conference of 2nd International Conference on Fundamental and Applied Sciences 2012, ICFAS 2012 ; Conference Date: 12 June 2012 Through 14 June 2012
abstract: Solvent resistant nanofiltration (SRNF) using polymer membranes has recently received enhanced attention due to the search for cleaner and more energy-efficient technologies. The large size of the rhodium tris(triphenylphosphine) HRh(CO)(PPh3)3 catalyst (>400 Da) - relative to other components of the hydroformylation reaction provides the opportunity for a membrane separation based on retention of the catalyst species while permeating the solvent. The compatibility of the solvent-polyimide membrane (DuraMem{trade mark, serif} 200 and DuraMem{trade mark, serif} 500) combinations was assessed in terms of the membrane stability in solvent plus non-zero solvent flux at 2.0 MPa. Good HRh(CO)(PPh 3)3 rejection (>0.95) and solvent fluxes of 9.9 L/m2·h1 at 2.0 MPa were obtained in the catalyst-ethyl acetate-DuraMem 500 system. The effect of pressure and catalyst concentration on the solvent flux and catalyst rejection was conducted on the catalyst-ethyl acetate-membrane systems. Increasing pressure substantially improved both solvent flux and catalyst rejection, while increasing catalyst concentration was found to be beneficial in terms of substantial increases in catalyst rejection without significantly affecting solvent flux. © 2012 American Institute of Physics.
date: 2012
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84874149815&doi=10.1063%2f1.4757480&partnerID=40&md5=0041a2073e25758d4ceec7ce7d94d922
id_number: 10.1063/1.4757480
full_text_status: none
publication: AIP Conference Proceedings
volume: 1482
place_of_pub: Kuala Lumpur
pagerange: 279-283
refereed: TRUE
isbn: 9780735410947
issn: 0094243X
citation:   Shaharun, M.S. and Mustafa, A.K. and Taha, M.F.  (2012) Nanofiltration of rhodium tris(triphenylphosphine) catalyst in ethyl acetate solution.  In: UNSPECIFIED.