TY - JOUR UR - https://www.scopus.com/inward/record.uri?eid=2-s2.0-34547691140&doi=10.1021%2fje060444w&partnerID=40&md5=02ed916045a4e3deb26d6a0bd85a6c10 TI - Experiment and correlation of liquid-liquid equilibria of an aqueous salt polymer system containing PEG6000 + sodium citrate SN - 00219568 ID - scholars250 A1 - Perumalsamy, M. A1 - Bathmalakshmi, A. A1 - Murugesan, T. Y1 - 2007/// N1 - cited By 35 SP - 1186 IS - 4 N2 - Liquid-Liquid equilibrium data were obtained for an aqueous two-phase system containing poly(ethylene glycol)-6000 (PEG6000) + sodium citrate + water at three different temperatures, 293.15, 303.15, and 313.15 K. An empirical equation relating the concentrations of PEG6000 and sodium citrate was used to fit the binodal curve, and the coefficients were estimated for the corresponding temperatures. The effect of temperature on binodal and tie line data was studied. The Othmer-Tobias and Bancraft equations were used to correlate the tie line compositions, and the parameters are reported. © 2007 American Chemical Society. VL - 52 JF - Journal of Chemical and Engineering Data AV - none EP - 1188 KW - Parameter estimation; Phase equilibria; Polyethylene glycols; Polymers; Sodium compounds KW - Bancraft equations; Empirical equation KW - Salts ER -