eprintid: 2295 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/00/22/95 datestamp: 2023-11-09 15:50:30 lastmod: 2023-11-09 15:50:30 status_changed: 2023-11-09 15:42:26 type: article metadata_visibility: show creators_name: Almadori, Y. creators_name: Alvarez, L. creators_name: Arenal, R. creators_name: Babaa, R. creators_name: Michel, T. creators_name: Le Parc, R. creators_name: Bantignies, J.-L. creators_name: Jouselme, B. creators_name: Palacin, S. creators_name: Hermet, P. creators_name: Sauvajol, J.-L. title: Charge transfer in conjugated oligomers encapsulated into carbon nanotubes ispublished: pub keywords: Carbon nanotubes; Charge transfer; Encapsulation; Excitation energy; High resolution transmission electron microscopy; Hybrid systems; Laser excitation; Light absorption; Nanotubes; Oligomers; Raman scattering; Single-walled carbon nanotubes (SWCN), Conjugated oligomer; Intensity loss; Low-excitation energy; Photoinduced process; Quaterthiophene; Raman; Resonance window; Spectroscopy data, Multiwalled carbon nanotubes (MWCN) note: cited By 5 abstract: This study deals with a hybrid system consisting in quaterthiophene derivative encapsulated inside single-walled and multiwalled carbon nanotubes. Investigations of the encapsulation step are performed by transmission electron microscopy. Raman spectroscopy data point out different behaviors depending on the laser excitation energy with respect to the optical absorption of quaterthiophene. At low excitation energy (far from the oligomer resonance window) there is no significant modification of the Raman spectra before and after encapsulation. By contrast, at high excitation energy (close to the oligomer resonance window), Raman spectra exhibit a G-band shift together with an important RBM intensity loss, suggesting a significant charge transfer between the inserted molecule and the host nanotubes. Those results suggest a photo induced process leading to a significant charge transfer. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. date: 2011 publisher: Wiley-VCH Verlag official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84868638403&doi=10.1002%2fpssb.201100094&partnerID=40&md5=140640f20c8aa5a1e5cb79b901cf3126 id_number: 10.1002/pssb.201100094 full_text_status: none publication: Physica Status Solidi (B) Basic Research volume: 248 number: 11 pagerange: 2560-2563 refereed: TRUE issn: 03701972 citation: Almadori, Y. and Alvarez, L. and Arenal, R. and Babaa, R. and Michel, T. and Le Parc, R. and Bantignies, J.-L. and Jouselme, B. and Palacin, S. and Hermet, P. and Sauvajol, J.-L. (2011) Charge transfer in conjugated oligomers encapsulated into carbon nanotubes. Physica Status Solidi (B) Basic Research, 248 (11). pp. 2560-2563. ISSN 03701972