eprintid: 2092
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/20/92
datestamp: 2023-11-09 15:50:16
lastmod: 2023-11-09 15:50:16
status_changed: 2023-11-09 15:41:59
type: article
metadata_visibility: show
creators_name: Kurnia, K.A.
creators_name: Mutalib, M.I.A.
creators_name: Ariwahjoedi, B.
title: Estimation of physicochemical properties of ionic liquids H 2N-C2mimBF4 and H2N-C 3mimBF4
ispublished: pub
keywords: Boiling temperature; Coefficient of thermal expansion; Critical temperatures; Density data; Experimental values; Guggenheim; Lattice energies; Molar enthalpy; Molecular volume; Physicochemical property; Standard molar entropy; Surface entropies; Tetrafluoroborates; Thermal expansion coefficients, Boiling liquids; Density of liquids; Enthalpy; Entropy; Ions; Surface properties; Surface tension; Thermal expansion, Ionic liquids
note: cited By 24
abstract: The density and surface tension of the ionic liquids 1-(2-aminoethyl)-3- methylimidazolium tetrafluoroborate, H2N-C2mimBF 4, and 1-(3-aminopropyl)-3-methylimidazolium tetrafluoroborate, H2N-C3mimBF4, were measured from (293.15 to 343.15) K. The coefficient of thermal expansion, molecular volume, standard molar entropy, and lattice energy were calculated using experimental density data. Meanwhile, the surface entropy and enthalpy were calculated from surface tension data. The critical temperature of the ionic liquids was estimated using the Guggenheim and Eötvos equations. The values were then used to estimate the boiling temperature of the ionic liquids according to methods of Rebelo et al. The molar enthalpy vaporization, �lgHm0, of the ionic liquid at 298.15 K was estimated using the methods of Kabo et al. According to the interstice model, the thermal expansion coefficient of the ionic liquids, α, was calculated, and the result was in very good agreement with the experimental value. © 2011 American Chemical Society.
date: 2011
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-79956148652&doi=10.1021%2fje200068x&partnerID=40&md5=1d4d171fccf70550465834ff5743a639
id_number: 10.1021/je200068x
full_text_status: none
publication: Journal of Chemical and Engineering Data
volume: 56
number: 5
pagerange: 2557-2562
refereed: TRUE
issn: 00219568
citation:   Kurnia, K.A. and Mutalib, M.I.A. and Ariwahjoedi, B.  (2011) Estimation of physicochemical properties of ionic liquids H 2N-C2mimBF4 and H2N-C 3mimBF4.  Journal of Chemical and Engineering Data, 56 (5).  pp. 2557-2562.  ISSN 00219568