eprintid: 20028 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/02/00/28 datestamp: 2024-06-04 14:19:46 lastmod: 2024-06-04 14:19:46 status_changed: 2024-06-04 14:16:26 type: article metadata_visibility: show creators_name: Bakr, Z.H. creators_name: Aboelazm, E.A.A. creators_name: Khe, C.S. creators_name: Ali, G.A.M. creators_name: Chong, K.F. title: Recycling the Spent Lithium-ion Battery into Nanocubes Cobalt Oxide Supercapacitor Electrode ispublished: pub keywords: Annealing; Anodes; Capacitance; Electrochemical electrodes; Honeycomb structures; Ions; Lithium-ion batteries; Nickel oxide; Recycling; Supercapacitor; Transition metal oxides; Transition metals; X ray diffraction, Annealing temperatures; Co3O4-NiO electrode; Electrochemical performance; Electrode material; Electrodeposition methods; Nanocubes; Spent lithium-ion batteries; Supercapacitor application; Supercapacitor electrodes; X- ray diffractions, Cobalt compounds, cobalt oxide nanocube; lithium ion; nanocube; nickel; unclassified drug, Article; controlled study; current density; cyclic voltammetry; electrochemistry; electrodeposition; foam; inductively coupled plasma mass spectrometry; recycling; room temperature; scanning electron microscopy; X ray diffraction note: cited By 0 abstract: Background: Cobalt oxide nanocubes have garnered significant attention as potential supercapacitor electrodes due to their unique structural and electrochemical properties. The spent lithium-ion batteries (LiBs) are considered as zero-cost source for cobalt oxide production. Objectives: The aim of this work is to recover cobalt oxide from spent LiBs and study its electrochemical performance as a supercapacitor electrode material. Methods: This study uses an electrodeposition method to obtain cobalt oxide honeycomb-like anodes coated on Ni foam substrates from spent Li-ion batteries for supercapacitors applications. The effect of annealing temperature on the cobalt oxide anode has been carefully investigated; 450ºC annealing temperature results in nanocubes on the surface of the cobalt oxide electrode. X-ray diffraction confirmed the formation of the Co3O4-NiO electrode. Results: The Co3O4-NiO nanocubes electrode has shown a high specific capacitance of 1400 F g-1 at 1 A g-1 and high capacitance retention of ~96 after 2250 cycles at a constant current density of 10 A g-1 compared to 900 F g-1 at 1 A g-1 as for prepared Co3O4 honeycomb. Conclusion: This strategy proves that the paramount importance of Co3O4-NiO nanocubes, meticulously synthesized at elevated temperatures, as a supremely effective active material upon deposition onto transition metal foam current collectors, establishing their indispensability for supercapacitor applications. © 2024 Bentham Science Publishers. date: 2024 official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85191943056&doi=10.2174%2f0115734137265230231020181833&partnerID=40&md5=09dda2a3bf31deb96b8186ef2f2471b5 id_number: 10.2174/0115734137265230231020181833 full_text_status: none publication: Current Nanoscience volume: 20 number: 6 pagerange: 820-829 refereed: TRUE citation: Bakr, Z.H. and Aboelazm, E.A.A. and Khe, C.S. and Ali, G.A.M. and Chong, K.F. (2024) Recycling the Spent Lithium-ion Battery into Nanocubes Cobalt Oxide Supercapacitor Electrode. Current Nanoscience, 20 (6). pp. 820-829.