eprintid: 19997
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/99/97
datestamp: 2024-06-04 14:19:44
lastmod: 2024-06-04 14:19:44
status_changed: 2024-06-04 14:16:22
type: article
metadata_visibility: show
creators_name: Diyan Mohd Ridzuan, N.
creators_name: Victor Ayodele, B.
creators_name: Najwa Abdul Talib, N.
creators_name: Shima Shaharun, M.
creators_name: Mohd Shariff, A.
creators_name: Naim Ahmad, K.
title: Synthesis and characterization of hydrophobic nickel catalyst supported on different oxides for continuous liquid phase catalytic exchange reaction
ispublished: pub
keywords: Catalyst supports; Crystallite size; Deuterium; Hydrophobicity; Particle size, Exchange reaction; Hydrophobic catalysts; Hydrophobics; Liquid phase catalytic exchange; Ni catalysts; Ni/SiO 2; Nickel catalyst; Particles sizes; Synthesis and characterizations; ]+ catalyst, Heavy water
note: cited By 0
abstract: Hydrophobic Ni catalysts supported on three metal oxides coated with PTFE namely Ni/SiO2/PTFE, Ni/Cr2O3/PTFE, and Ni/Al2O3/PTFE were used in liquid-phase catalytic exchange (LPCE) reactions to enrich hydrogen isotope and produce deuterium oxide (heavy water). Wet impregnation method was employed to prepare the Ni/SiO2, Ni/Cr2O3, and Ni/Al2O3 before PTFE coating. The as prepared catalysts were characterized using different characterization techniques and their performances were evaluated in LPCE reaction using a continuous reactor. The performance evaluation based on the D2O yield can be ranked as Ni/Al2O3/PTFE > Ni/Cr2O3/PTFE > Ni/SiO2/PTFE > Ni/PTFE. The catalysts� performances are strongly associated with the crystallite size, particle size, hydrophobicity, surface area, pore size, and metal-support interaction. Since isotope exchange requires a dry catalyst surface, the catalyst's hydrophobicity plays a crucial role. In addition, the catalyst support improves the LPCE reaction efficiency, as the most efficient catalyst, Ni/Al2O3/PTFE, yielded 1220 ppm D2O, compared to 520 ppm for the benchmark catalyst, Ni/PTFE. The characterization results reveal that Ni/Al2O3/PTFE outperformed the other catalysts due to its low crystallite size (D = 23.04 nm), high hydrophobicity (WCA = 139.23°), higher surface area (16.31 m2g�1), small pores (pore size = 6.18 nm), and lowest average Ni particle size (40.89 nm). © 2024 The Korean Society of Industrial and Engineering Chemistry
date: 2024
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85193474168&doi=10.1016%2fj.jiec.2024.05.032&partnerID=40&md5=51d6f4e77d067ba34356c76289864867
id_number: 10.1016/j.jiec.2024.05.032
full_text_status: none
publication: Journal of Industrial and Engineering Chemistry
refereed: TRUE
citation:   Diyan Mohd Ridzuan, N. and Victor Ayodele, B. and Najwa Abdul Talib, N. and Shima Shaharun, M. and Mohd Shariff, A. and Naim Ahmad, K.  (2024) Synthesis and characterization of hydrophobic nickel catalyst supported on different oxides for continuous liquid phase catalytic exchange reaction.  Journal of Industrial and Engineering Chemistry.