<> "The repository administrator has not yet configured an RDF license."^^ . <> . . . "Kinetic & thermodynamic studies of green fuel additive solketal from crude glycerol over metakaolin clay catalyst"^^ . "Biodiesel synthesis produces about 10 glycerol as a byproduct, prompting environmental concerns. The utilization of crude glycerol into valuable products requires an Eco-friendly technique. This study depicts glycerol acetalization using acetone and novel catalyst acid-treated metakaolin clay. Raw kaolin clay was calcined at 600 °C and treated with acid at 102 °C for 3 h. Afterward, acid activated clay was filtrate and dried in oven to remove moisture content. The catalyst prepared with a 5 M solution of sulfuric acid exhibited the highest surface area of 82.33 m2. g�1 and gave the highest yield (80 ) of Solketal with 73 of glycerol conversion under optimum conditions. The ketalization reaction of Solketal synthesis was studied in terms of thermodynamics and kinetics. A Langmuir-Hinshelwood rate expression based on two-parameter kinetic law was used in this study. From the kinetic studies, activation energies (EA) of forward and backward reactions were found to be K1 = 39.23 kJ. mol�1 and K2 = 35.70 kJ. mol�1 respectively. Furthermore, reaction was exothermic having an enthalpy of �Ho = �18.86 kJ. mol�1 and the entropy �So = �0.1 kJ. mol�1 calculated from this process. Solketal derived from sustainable sources such as bio-glycerol and biomass-based acetone, has a wide range of uses as fuel additives and medicines industry. This research marks a significant advancement in the development of a continuous synthesis technique for Solketal and its recovery from glycerol-acetone mixtures. © 2023 The Authors"^^ . "2024" . . "181" . . "Biomass and Bioenergy"^^ . . . . . . . . . . . . . . . . . . . . . . . . . . "B.B."^^ . "Abdullah"^^ . "B.B. Abdullah"^^ . . "I."^^ . "Zahid"^^ . "I. Zahid"^^ . . "R."^^ . "Shamsuddin"^^ . "R. Shamsuddin"^^ . . "M.H."^^ . "Nazir"^^ . "M.H. Nazir"^^ . . "M."^^ . "Ameen"^^ . "M. Ameen"^^ . . "M."^^ . "Ayoub"^^ . "M. Ayoub"^^ . . "F."^^ . "Sher"^^ . "F. Sher"^^ . . . . . "HTML Summary of #19926 \n\nKinetic & thermodynamic studies of green fuel additive solketal from crude glycerol over metakaolin clay catalyst\n\n" . "text/html" . .