<> "The repository administrator has not yet configured an RDF license."^^ . <> . . . "The role of bio-inspired ZnO nanoparticles in the modification of MIL101(Cr) properties for visible light degradation of phenanthrene"^^ . "MIL-101(Cr) metal-organic frameworks and novel zinc oxide-MIL101(Cr) metal organic frameworks (ZnO-MIL101(Cr)) were prepared by hydrothermal technique at 160 °C and 220 °C for photodegradation of phenanthrene (PHE) in visible light. X-ray diffraction (XRD) analysis indicated a reduction in crystallite sizes of ZnO-MIL101(Cr) when compared to MIL101(Cr). However, incorporation of zinc oxide (ZnO) did not disrupt the MIL101(Cr) structure. ZnO-MIL101(Cr) exhibited high BET surface area (>1000 m2/g) when compared to MIL-101(Cr). These composites have lower bandgaps of �3.20 eV, than MIL-101(Cr) (3.5 eV). Optical studies reveal that incorporation of ZnO into MIL101(Cr) delays recombination of electron-hole pairs. These factors lead to ZnO-MIL101(Cr) having similar PHE degradation (98), however within a shorter time when compared to MIL101(Cr). Catalysts followed the pseudo first-order kinetic model with ZnO-MIL101@220 °C having a rate constant of 2.83 � 10�2 min�1. This is 2.3� and 1.1� higher than ZnO and the respective MIL101(Cr), correspondingly. Scavenging tests reveal that the hydroxyl radical (�OH) is the primary reactive species for PHE degradation. A degradation mechanism is proposed based on this finding. © 2023"^^ . "2024" . . "187" . . "Catalysis Communications"^^ . . . . . . . . . . . . . . . . . . . . "U.A."^^ . "Adamu"^^ . "U.A. Adamu"^^ . . "N.H.H."^^ . "Abu Bakar"^^ . "N.H.H. Abu Bakar"^^ . . "N.S."^^ . "Sambudi"^^ . "N.S. Sambudi"^^ . . "A."^^ . "Iqbal"^^ . "A. Iqbal"^^ . . "Z.U."^^ . "Zango"^^ . "Z.U. Zango"^^ . . . . . "HTML Summary of #19915 \n\nThe role of bio-inspired ZnO nanoparticles in the modification of MIL101(Cr) properties for visible light degradation of phenanthrene\n\n" . "text/html" . .