eprintid: 19797
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/97/97
datestamp: 2024-06-04 14:19:32
lastmod: 2024-06-04 14:19:32
status_changed: 2024-06-04 14:15:50
type: article
metadata_visibility: show
creators_name: Abu Talip, R.A.
creators_name: Yahya, W.Z.N.
creators_name: Mohamed, N.M.
creators_name: Zaki, Y.H.
creators_name: Ramly, K.
creators_name: Zaine, S.N.A.
creators_name: Bustam, M.A.
creators_name: Singh, P.K.
title: A performance enhancement of dye-sensitized solar cells using pyrazolium-based ionic liquids electrolytes vs imidazolium-based ionic liquids electrolytes
ispublished: pub
keywords: Conversion efficiency; Dye-sensitized solar cells; Ionic conductivity; Ionic liquids; Ions, Dye- sensitized solar cells; Heteroaromatics; Heteroatoms; Imidazolium; Imidazolium-based ionic liquid; Ionic liquid electrolytes; Performance enhancements; Property; Pyrazolia ionic liquid; Rings structure, Electrolytes
note: cited By 0
abstract: Pyrazolium-based ionic liquids (ILs) having similar heteroaromatic ring structure as imidazolium are distinguishable by the position of the heteroatom (nitrogens) but are less delved into their properties and their capability in dye-sensitized solar cells (DSSCs). Herein, alkylpyrazolium and alkylimidazolium-based ionic liquids having iodide and triiodide anions were compared in terms of their properties namely viscosity, ionic conductivity, and performance as electrolytes in dye-sensitized solar cells (DSSCs). Furthermore, the effect of varying the concentration of the iodide and triiodide anions was also scrutinized. The DSSCs having pyrazolium-based ILs electrolytes showed considerably higher fill factor (FF) and short circuit current (Jsc) than the cells containing imidazolium-based ILs electrolytes attributable to the high ionic conductivities. The cells with butylpyrazolium 4-1-pzI and 4-1-pzI3 ILs showed the highest power conversion efficiency of 4.76 % with an improvement of 62.4 % compared to corresponding imidazolium ILs electrolytes, owing to the high current density (Jsc). The concentration of the iodide and triiodide redox couple was found to affect the dye regeneration and recombination process as elucidated by electrochemical impedance spectra. The high concentration of triiodide has caused cell efficiency to decrease by more than 50 % with low Jsc, electron diffusion (Deff), and triiodide ions diffusion (DI3-) indicating poor mass transport. The best concentrations for iodide and triiodide found in this study are 0.45 M and 0.064 M, respectively. Hence, pyrazolium-based ILs have high potential to be used as electrolytes for DSSCs applications. © 2024 Elsevier B.V.
date: 2024
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85184992955&doi=10.1016%2fj.molliq.2024.124214&partnerID=40&md5=65eee4626d72b828ea2525b507feaa97
id_number: 10.1016/j.molliq.2024.124214
full_text_status: none
publication: Journal of Molecular Liquids
volume: 398
refereed: TRUE
citation:   Abu Talip, R.A. and Yahya, W.Z.N. and Mohamed, N.M. and Zaki, Y.H. and Ramly, K. and Zaine, S.N.A. and Bustam, M.A. and Singh, P.K.  (2024) A performance enhancement of dye-sensitized solar cells using pyrazolium-based ionic liquids electrolytes vs imidazolium-based ionic liquids electrolytes.  Journal of Molecular Liquids, 398.