eprintid: 19766 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/01/97/66 datestamp: 2024-06-04 14:19:30 lastmod: 2024-06-04 14:19:30 status_changed: 2024-06-04 14:15:46 type: article metadata_visibility: show creators_name: Abioye, K.J. creators_name: Harun, N.Y. creators_name: Sufian, S. creators_name: Yusuf, M. creators_name: Jagaba, A.H. creators_name: Waqas, S. creators_name: Ayodele, B.V. creators_name: Kamyab, H. creators_name: Alam, M. creators_name: Gupta, M. creators_name: Gill, H.S. creators_name: Rezania, S. creators_name: Chelliapan, S. creators_name: Kang, K. title: Optimization of syngas production from co-gasification of palm oil decanter cake and alum sludge: An RSM approach with char characterization ispublished: pub keywords: Air; Calcite; Calcium carbonate; Flow rate; Gasification; Palm oil; Surface properties; Synthesis gas, Air flow-rate; Alum sludge; Biomass wastes; Char residues; Co-gasification; Fourier; Optimisations; Particles sizes; Response-surface methodology; Syngas production, Particle size, calcium carbonate; carbon dioxide; charcoal; chloride; hydrogen; oxygen; palm oil; palm oil decanter cake; silicon; synfuel; unclassified drug; aluminum potassium sulfate; aluminum sulfate; palm oil, airflow; biomass; calcium carbonate; chemical composition; design; optimization; particle size; response surface methodology, airflow; alum sludge; analysis of variance; Article; chemical bond; chemical composition; chemical structure; controlled study; correlation analysis; experimental design; field emission scanning electron microscopy; flow rate; Fourier transform infrared spectroscopy; furnace; gasification; microphotography; nonhuman; particle size; porosity; process optimization; regression analysis; sample; sludge; surface property; temperature sense; waste-to-energy; biomass; chemistry; gas; sewage; temperature, Alum Compounds; Biomass; Gases; Palm Oil; Sewage; Temperature note: cited By 1 abstract: The study explores co-gasification of palm oil decanter cake and alum sludge, investigating the correlation between input variables and syngas production. Operating variables, including temperature (700�900 °C), air flow rate (10�30 mL/min), and particle size (0.25�2 mm), were optimized to maximize syngas production using air as the gasification agent in a fixed bed horizontal tube furnace reactor. Response Surface Methodology with the Box-Behnken design was used employed for optimization. Fourier Transformed Infra-Red (FTIR) and Field Emission Scanning Electron Microscopic (FESEM) analyses were used to analyze the char residue. The results showed that temperature and particle size have positive effects, while air flow rate has a negative effect on the syngas yield. The optimal CO + H2 composition of 39.48 vol was achieved at 900 °C, 10 mL/min air flow rate, and 2 mm particle size. FTIR analysis confirmed the absence of C�Cl bonds and the emergence of Si�O bonds in the optimized char residue, distinguishing it from the raw sample. FESEM analysis revealed a rich porous structure in the optimized char residue, with the presence of calcium carbonate (CaCO3) and aluminosilicates. These findings provide valuable insights for sustainable energy production from biomass wastes. © 2023 Elsevier Inc. date: 2024 official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85181827619&doi=10.1016%2fj.envres.2023.118027&partnerID=40&md5=f36075133fd1f8da1a0c953c43177006 id_number: 10.1016/j.envres.2023.118027 full_text_status: none publication: Environmental Research volume: 246 refereed: TRUE citation: Abioye, K.J. and Harun, N.Y. and Sufian, S. and Yusuf, M. and Jagaba, A.H. and Waqas, S. and Ayodele, B.V. and Kamyab, H. and Alam, M. and Gupta, M. and Gill, H.S. and Rezania, S. and Chelliapan, S. and Kang, K. (2024) Optimization of syngas production from co-gasification of palm oil decanter cake and alum sludge: An RSM approach with char characterization. Environmental Research, 246.