eprintid: 19691
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/96/91
datestamp: 2024-06-04 14:19:25
lastmod: 2024-06-04 14:19:25
status_changed: 2024-06-04 14:15:37
type: article
metadata_visibility: show
creators_name: Javaid, M.A.
creators_name: Cheema, S.A.
creators_name: Nasir, N.
creators_name: Ahmad, S.
creators_name: Hussain, M.T.
creators_name: Tanveer, Z.
creators_name: Mustafa, M.Z.U.
creators_name: Tahir, U.
creators_name: Ali, S.
title: Exploring the synergistic effect of carboxymethyl cellulose and chitosan in enhancing thermal stability of polyurethanes through statistical mixture design approach
ispublished: pub
keywords: Cellulose; Chitosan; Thermodynamic stability; Thermogravimetric analysis, Carboxymethyl cellulose; Carboxymethyl chitosan; Chain extenders; Design approaches; Hydroxyl terminated polybutadienes; Hydroxyl-terminated polybutadiene; Mixture design; Research papers; Synergistic effect; Wide temperature ranges, Design of experiments, 1,3 butadiene; carboxymethylcellulose; chitosan; dimethyl sulfoxide; hydrogen peroxide; isophorone; isophorone diisocyanate; polyurethan; unclassified drug, Article; chemical reaction; chemical structure; differential scanning calorimetry; drug potentiation; drug synthesis; Fourier transform infrared spectroscopy; synergistic effect; thermogravimetry; thermostability; chemistry; temperature, Carboxymethyl Cellulose; Chitosan; Design; Gravimetry; Polyurethanes; Samples; Thermal Analysis; Thermal Stability, Carboxymethylcellulose Sodium; Chitosan; Polyurethanes; Spectroscopy, Fourier Transform Infrared; Temperature; Thermogravimetry
note: cited By 0
abstract: The thermal stability of polyurethanes, known for its limitations, was addressed in this research by seeking improvement through the introduction of carbohydrate-based chain extenders. In this research paper, we systematically sought to improve the thermal resistance of polyurethanes by incorporating carboxymethyl cellulose and chitosan, representing a pioneering application of the mixture design approach in their preparation. In this synthesis, hydroxyl-terminated polybutadiene and isophorone diisocyanate (IPDI) were reacted to prepare �NCO terminated prepolymer, which was subsequently reacted with varying mole ratios of CMC and CSN to develop a series of five PU samples. The prepared PU samples were characterized using the Fourier-transformed infrared spectroscopic technique. Thermal pyrolysis of PU samples was examined using thermal gravimetric analysis (TGA). It was observed that, among all the samples, PUS-3 showed remarkable thermal stability over a wide temperature range. A comprehensive statistical analysis was conducted to substantiate the experimental findings. It was estimated that CMC and CSN significantly enhance the thermal stability of the samples when involved in an interaction fashion. The ANOVA Table for the mixture design demonstrates that over 90  of the total variation in thermal stability is explained by the mixture model across a wide temperature range. Moreover, PSU-3 exhibited 4  more thermal stability over a wide range of temperatures on average, as compared to contemporary samples. © 2024 Elsevier B.V.
date: 2024
publisher: Elsevier B.V.
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85190534247&doi=10.1016%2fj.ijbiomac.2024.131441&partnerID=40&md5=57d27fbde1981a3ca8a96d6ddee87444
id_number: 10.1016/j.ijbiomac.2024.131441
full_text_status: none
publication: International Journal of Biological Macromolecules
volume: 267
refereed: TRUE
issn: 01418130
citation:   Javaid, M.A. and Cheema, S.A. and Nasir, N. and Ahmad, S. and Hussain, M.T. and Tanveer, Z. and Mustafa, M.Z.U. and Tahir, U. and Ali, S.  (2024) Exploring the synergistic effect of carboxymethyl cellulose and chitosan in enhancing thermal stability of polyurethanes through statistical mixture design approach.  International Journal of Biological Macromolecules, 267.   ISSN 01418130