eprintid: 19412
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/94/12
datestamp: 2024-06-04 14:11:52
lastmod: 2024-06-04 14:11:52
status_changed: 2024-06-04 14:05:40
type: article
metadata_visibility: show
creators_name: Abbas Adam, A.
creators_name: Soleimani, H.
creators_name: Bin Abd. Shukur, M.F.
creators_name: Ojur Dennis, J.
creators_name: Abubakar Abdulkadir, B.
creators_name: Mudassir Hassan, Y.
creators_name: Yusuf, J.Y.
creators_name: Bt Shamsuri, N.A.
creators_name: Obaidur Rahman, M.
creators_name: Ilyasu Rafukka, S.
title: Structural behavior and ion dynamics of methylcellulose/tri-potassium phosphate-based solid biopolymeric electrolytes
ispublished: pub
keywords: Charge transfer; Fourier transform infrared spectroscopy; Fourier transforms; Potassium compounds; Solid electrolytes; X ray diffraction analysis, Behavior dynamics; Electrochemical devices; Host matrices; Ion dynamics; Methylcellulose; Potential stability; Solution-cast; Structural behaviors; Transference number; Ultra-sonication, Biopolymers
note: cited By 2
abstract: In this article, the complexation of methylcellulose (MC) with tri-potassium phosphate (K3PO4) is investigated using an ultrasonication-assisted solution cast process. X-ray diffraction (XRD) analysis indicates that varying concentrations of K3PO4 salt (7�35 wt.) disrupt the crystalline segment of the MC host matrix. The considerable shift in the intensity and orientation of the Fourier transforms infrared spectroscopy (FTIR) transmittance bands indicate the establishment of a charge-transfer entanglement between the polymer host and the dispersed salt. The optimum sample (28 wt.) exhibits a high ionic conductivity of 1.74 � 10�5 S cm�1, potential stability of 3.48 V, and a cation transference number (ti) of 0.945. These findings show the relevance of the developed SPEs for possible application in electrochemical devices. © 2022 Taylor & Francis Group, LLC.
date: 2023
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85145398227&doi=10.1080%2f15421406.2022.2160901&partnerID=40&md5=d1015b901ac4d47f5477d00dd1debd3e
id_number: 10.1080/15421406.2022.2160901
full_text_status: none
publication: Molecular Crystals and Liquid Crystals
volume: 759
number: 1
pagerange: 29-43
refereed: TRUE
citation:   Abbas Adam, A. and Soleimani, H. and Bin Abd. Shukur, M.F. and Ojur Dennis, J. and Abubakar Abdulkadir, B. and Mudassir Hassan, Y. and Yusuf, J.Y. and Bt Shamsuri, N.A. and Obaidur Rahman, M. and Ilyasu Rafukka, S.  (2023) Structural behavior and ion dynamics of methylcellulose/tri-potassium phosphate-based solid biopolymeric electrolytes.  Molecular Crystals and Liquid Crystals, 759 (1).  pp. 29-43.