TY  - JOUR
EP  - 43
A1  - Abbas Adam, A.
A1  - Soleimani, H.
A1  - Bin Abd. Shukur, M.F.
A1  - Ojur Dennis, J.
A1  - Abubakar Abdulkadir, B.
A1  - Mudassir Hassan, Y.
A1  - Yusuf, J.Y.
A1  - Bt Shamsuri, N.A.
A1  - Obaidur Rahman, M.
A1  - Ilyasu Rafukka, S.
Y1  - 2023///
TI  - Structural behavior and ion dynamics of methylcellulose/tri-potassium phosphate-based solid biopolymeric electrolytes
ID  - scholars19412
SP  - 29
IS  - 1
KW  - Charge transfer; Fourier transform infrared spectroscopy; Fourier transforms; Potassium compounds; Solid electrolytes; X ray diffraction analysis
KW  -  Behavior dynamics; Electrochemical devices; Host matrices; Ion dynamics; Methylcellulose; Potential stability; Solution-cast; Structural behaviors; Transference number; Ultra-sonication
KW  -  Biopolymers
N1  - cited By 2
VL  - 759
JF  - Molecular Crystals and Liquid Crystals
N2  - In this article, the complexation of methylcellulose (MC) with tri-potassium phosphate (K3PO4) is investigated using an ultrasonication-assisted solution cast process. X-ray diffraction (XRD) analysis indicates that varying concentrations of K3PO4 salt (7â??35 wt.) disrupt the crystalline segment of the MC host matrix. The considerable shift in the intensity and orientation of the Fourier transforms infrared spectroscopy (FTIR) transmittance bands indicate the establishment of a charge-transfer entanglement between the polymer host and the dispersed salt. The optimum sample (28 wt.) exhibits a high ionic conductivity of 1.74 Ã? 10â??5 S cmâ??1, potential stability of 3.48 V, and a cation transference number (ti) of 0.945. These findings show the relevance of the developed SPEs for possible application in electrochemical devices. © 2022 Taylor & Francis Group, LLC.
AV  - none
UR  - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85145398227&doi=10.1080%2f15421406.2022.2160901&partnerID=40&md5=d1015b901ac4d47f5477d00dd1debd3e
ER  -