relation: https://khub.utp.edu.my/scholars/19412/
title: Structural behavior and ion dynamics of methylcellulose/tri-potassium phosphate-based solid biopolymeric electrolytes
creator: Abbas Adam, A.
creator: Soleimani, H.
creator: Bin Abd. Shukur, M.F.
creator: Ojur Dennis, J.
creator: Abubakar Abdulkadir, B.
creator: Mudassir Hassan, Y.
creator: Yusuf, J.Y.
creator: Bt Shamsuri, N.A.
creator: Obaidur Rahman, M.
creator: Ilyasu Rafukka, S.
description: In this article, the complexation of methylcellulose (MC) with tri-potassium phosphate (K3PO4) is investigated using an ultrasonication-assisted solution cast process. X-ray diffraction (XRD) analysis indicates that varying concentrations of K3PO4 salt (7�35 wt.) disrupt the crystalline segment of the MC host matrix. The considerable shift in the intensity and orientation of the Fourier transforms infrared spectroscopy (FTIR) transmittance bands indicate the establishment of a charge-transfer entanglement between the polymer host and the dispersed salt. The optimum sample (28 wt.) exhibits a high ionic conductivity of 1.74 � 10�5 S cm�1, potential stability of 3.48 V, and a cation transference number (ti) of 0.945. These findings show the relevance of the developed SPEs for possible application in electrochemical devices. © 2022 Taylor & Francis Group, LLC.
date: 2023
type: Article
type: PeerReviewed
identifier:   Abbas Adam, A. and Soleimani, H. and Bin Abd. Shukur, M.F. and Ojur Dennis, J. and Abubakar Abdulkadir, B. and Mudassir Hassan, Y. and Yusuf, J.Y. and Bt Shamsuri, N.A. and Obaidur Rahman, M. and Ilyasu Rafukka, S.  (2023) Structural behavior and ion dynamics of methylcellulose/tri-potassium phosphate-based solid biopolymeric electrolytes.  Molecular Crystals and Liquid Crystals, 759 (1).  pp. 29-43.      
relation: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85145398227&doi=10.1080%2f15421406.2022.2160901&partnerID=40&md5=d1015b901ac4d47f5477d00dd1debd3e
relation: 10.1080/15421406.2022.2160901
identifier: 10.1080/15421406.2022.2160901