eprintid: 18958
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/89/58
datestamp: 2024-06-04 14:11:24
lastmod: 2024-06-04 14:11:24
status_changed: 2024-06-04 14:04:31
type: article
metadata_visibility: show
creators_name: Chowdhury, N.E.
creators_name: Yusoff, P.S.M.B.M.
creators_name: Mustapha, M.B.
creators_name: Lah, N.F.B.C.
title: INFLUENCE OF THE COMPOSITION OF MODIFIED LIGNIN-EPOXY COATING ON CORROSION RESISTANCE USING RESPONSE SURFACE METHODOLOGY
ispublished: pub
note: cited By 0
abstract: Bisphenol A epichlorohydrin (BPA-EC) as a resin, and cycloaliphatic amine (CAA) as a curing agent, are conventionally used for formulating epoxy coatings for industrial applications. However, due to its noticeable toxicity, alternative curing agents such as aminopropyl triethoxysilane (APTES) can be used instead of CAA. Moreover, BPA-EC can be partially replaced by kraft lignin. In this study, the influences of APTES, BPA-EC, and kraft lignin on corrosion resistance were analyzed using the robust statistical analytical capabilities of the existing optimization models. Response surface methodology and the Box-Behnken design model were used to investigate the respective and cumulative effect of each element. Initially, the model has a P value of 0.0037, with some of the terms not significant. Thus, a modified model has been introduced keeping only the significant terms. Finally, a P-value of 0.0004 has been achieved. Although the model showed a non-linear association for all the constituent elements, no cumulative relation has been found. However, statistics showed that BPA-EC is a necessary element for the coating to be corrosion-resistive, as corrosion resistance of the coating is proportional to the quantity of BPA-EC in the coating. Thus, the study concludes that in an attempt to decrease toxicity from the proposed APTES-cured coating matrix, BPA-EC cannot be completely replaced by lignin. © 2023 Oles Honchar Dnipro National University.
date: 2023
publisher: Oles Honchar Dnipro National University
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85183612519&doi=10.15421%2fjchemtech.v31i4.290101&partnerID=40&md5=84113b944874b2c6c999ccdef5ce4768
id_number: 10.15421/jchemtech.v31i4.290101
full_text_status: none
publication: Journal of Chemistry and Technologies
volume: 31
number: 4
pagerange: 844-854
refereed: TRUE
issn: 26632934
citation:   Chowdhury, N.E. and Yusoff, P.S.M.B.M. and Mustapha, M.B. and Lah, N.F.B.C.  (2023) INFLUENCE OF THE COMPOSITION OF MODIFIED LIGNIN-EPOXY COATING ON CORROSION RESISTANCE USING RESPONSE SURFACE METHODOLOGY.  Journal of Chemistry and Technologies, 31 (4).  pp. 844-854.  ISSN 26632934