relation: https://khub.utp.edu.my/scholars/18768/ title: Novel LiAlO2 Material for Scalable and Facile Lithium Recovery Using Electrochemical Ion Pumping creator: Elmakki, T. creator: Zavahir, S. creator: Hafsa, U. creator: Al-Sulaiti, L. creator: Ahmad, Z. creator: Chen, Y. creator: Park, H. creator: Shon, H.K. creator: Ho, Y.-C. creator: Han, D.S. description: In this study, α-LiAlO2 was investigated for the first time as a Li-capturing positive electrode material to recover Li from aqueous Li resources. The material was synthesized using hydrothermal synthesis and air annealing, which is a low-cost and low-energy fabrication process. The physical characterization showed that the material formed an α-LiAlO2 phase, and electrochemical activation revealed the presence of AlO2* as a Li deficient form that can intercalate Li+. The AlO2*/activated carbon electrode pair showed selective capture of Li+ ions when the concentrations were between 100 mM and 25 mM. In mono salt solution comprising 25 mM LiCl, the adsorption capacity was 8.25 mg g�1, and the energy consumption was 27.98 Wh mol Li�1. The system can also handle complex solutions such as first-pass seawater reverse osmosis brine, which has a slightly higher concentration of Li than seawater at 0.34 ppm. © 2023 by the authors. date: 2023 type: Article type: PeerReviewed identifier: Elmakki, T. and Zavahir, S. and Hafsa, U. and Al-Sulaiti, L. and Ahmad, Z. and Chen, Y. and Park, H. and Shon, H.K. and Ho, Y.-C. and Han, D.S. (2023) Novel LiAlO2 Material for Scalable and Facile Lithium Recovery Using Electrochemical Ion Pumping. Nanomaterials, 13 (5). relation: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85149777397&doi=10.3390%2fnano13050895&partnerID=40&md5=d3d99e23617ea31deaa8cd0d0a4574ff relation: 10.3390/nano13050895 identifier: 10.3390/nano13050895