eprintid: 18631 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/01/86/31 datestamp: 2024-06-04 14:10:58 lastmod: 2024-06-04 14:10:58 status_changed: 2024-06-04 14:03:45 type: article metadata_visibility: show creators_name: Rasool, M.H. creators_name: Ahmad, M. creators_name: Ayoub, M. creators_name: Abbas, M.A. title: A Novel Ascorbic Acid Based Natural Deep Eutectic Solvent as a Drilling Mud Additive for Shale Stabilization ispublished: pub keywords: Additives; Ascorbic acid; Biodegradability; Chlorine compounds; Drilling fluids; Eutectics; Infill drilling; Minerals; Potassium compounds; Shale; Silicates; Solvents, Clay mineralogy; Deep eutectic solvents; Drilling fluid additives; Drilling fluid property; Natural deep eutectic solvent; Research groups; Shale formation; Shale swelling; Water-based muds; Wellbore instability, Ionic liquids note: cited By 12 abstract: During drilling, almost 70 of wellbore instability issues result from the encountering of shale formations. Various additives such as salts, silicates, and polymers are used in water-based mud to enhance its shale-inhibition capability; however, such additives have certain limitations. Lately, ionic liquids and deep eutectic solvents (DES) have been used by various research groups as shale inhibitors in drilling fluid due to their biodegradability and efficacy. However, their popularity faded when a natural derivative of DES, i.e., Natural Deep Eutectic solvent (NADES), came into the picture. This research utilizes the in-house-prepared Ascorbic acid and Glycerine (AA:Gly)-based NADES as a drilling fluid additive for shale inhibition and compares its efficacy with counterpart inhibitors such as KCl, imidazolium-based ionic liquid, and Choline Chloride-based DES. The results show that 3 NADES improved the overall Yield point to Plastic viscosity ratio, with a 39.69 decline in mud cake thickness and a 28 decline in the filtrate volume of drilling mud. Along with improved drilling fluid properties, 3 NADES resulted in 77.77 shale inhibition and 87 shale recovery. Surface tension, d-spacing, zeta potential, and FESEM have been conducted to justify and elucidate the inherent mechanism behind the working of NADES as a drilling fluid additive and clay stabilizer. Thus, Ascorbic acid-based NADES is recommended as a potential non-toxic and cheap drilling fluid additive to improve drilling fluid properties and clay stability. © 2023 by the authors. date: 2023 official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85156155399&doi=10.3390%2fpr11041135&partnerID=40&md5=e550fb3ab9ecc4015b008b5f0f6fa2f7 id_number: 10.3390/pr11041135 full_text_status: none publication: Processes volume: 11 number: 4 refereed: TRUE citation: Rasool, M.H. and Ahmad, M. and Ayoub, M. and Abbas, M.A. (2023) A Novel Ascorbic Acid Based Natural Deep Eutectic Solvent as a Drilling Mud Additive for Shale Stabilization. Processes, 11 (4).