eprintid: 18569
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/85/69
datestamp: 2024-06-04 14:10:53
lastmod: 2024-06-04 14:10:53
status_changed: 2024-06-04 14:03:38
type: article
metadata_visibility: show
creators_name: Abdul Manaf, A.S.
creators_name: Mostapha, M.
creators_name: Ameen, M.
creators_name: Yusup, S.
creators_name: Amran, N.A.
title: Optimization Study of Glucose Synthesis to 5-Hydroxymethylfurfural (5-HMF) by Using Low Transition-Temperature Mixtures (LTTM)
ispublished: pub
note: cited By 2
abstract: 5-Hydroxymethylfurfural (5-HMF) is a potential value-added product gaining popularity due to its wide range of applications. Glucose is widely used for 5-HMF production because it is abundant and more cost-effective than other resources. In the current research, a combination of microwave irradiation and low transition-temperature mixture (LTTM) for 5-HMF production was sustainably created. A preliminary study was conducted to derive 5-HMF using LTTM as a green solvent in various ratios of glucose: LTTM (MA/ChCl): water (10:100:15) and (10:48:100) via microwave heating at 90 °C for 10�60 min reaction time. The product analysis revealed that the 10:100:15 combination ratio of glucose: LTTM: water produced more 5-HMF (20.5) than the 10:48:100 (0.28) ratio. Following the preliminary results, an optimization study was conducted, focusing on the reaction temperature, LTTM mass, and water to assess the impact on 5-HMF yield and glucose conversion, using CCD in Design-Expert software. The quadratic model fit for 5-HMF yield and the 2FI model for glucose conversion yielded R2 values of 0.9861 and 0.8610, respectively. Both responses had a significant p value of 0.0061 for glucose conversion and <0.0001 for 5-HMF yield. An optimum point was achieved at 100 °C, 100 g of LTTM, and 20 g of water, with an expected 5-HMF yield and glucose conversion of 45.77 and 69.03, respectively. © 2023 by the authors.
date: 2023
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85160738692&doi=10.3390%2fcatal13050829&partnerID=40&md5=657ccf78b255baabce1845f19870f495
id_number: 10.3390/catal13050829
full_text_status: none
publication: Catalysts
volume: 13
number: 5
refereed: TRUE
citation:   Abdul Manaf, A.S. and Mostapha, M. and Ameen, M. and Yusup, S. and Amran, N.A.  (2023) Optimization Study of Glucose Synthesis to 5-Hydroxymethylfurfural (5-HMF) by Using Low Transition-Temperature Mixtures (LTTM).  Catalysts, 13 (5).