eprintid: 1850 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/00/18/50 datestamp: 2023-11-09 15:50:01 lastmod: 2023-11-09 15:50:01 status_changed: 2023-11-09 15:41:29 type: article metadata_visibility: show creators_name: Ali, S. creators_name: Zabidi, N.A.M. creators_name: Subbarao, D. title: Development of niobium-promoted cobalt catalysts on carbon nanotubes for Fischer-Tropsch synthesis ispublished: pub keywords: CNTs; Cobalt Catalyst; Cobalt-based catalysts; Fischer Tropsch; Fixed-bed; Micro-reactor; Nitrogen adsorption; Wet impregnation method; XRD, Carbon nanotubes; Catalysts; Cobalt; Gas adsorption; Methane; Niobium, Fischer-Tropsch synthesis note: cited By 5 abstract: Cobalt-based catalysts were prepared by a wet impregnation method on carbon nanotubes (CNTs) support and promoted with niobium. Samples were characterized by nitrogen adsorption, TEM, XRD, TPR, TPO and H 2-TPD. Addition of niobium increased the dispersion of cobalt but decreased the catalysts reducibility. Fischer-Tropsch synthesis (FTS) was carried out in a fixed-bed microreactor at 543 K, 1 atm and H 2/CO = 2 for 5 h. Addition of niobium enhanced the C 5+ hydrocarbons selectivity by 39 and reduced methane selectivity by 59. These effects were more pronounced for 0.04Nb/Co/CNTs catalyst, compared with those observed for other niobium compositions. © 2011 CAS/DICP. All rights reserved. date: 2011 official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-83455246790&doi=10.1016%2fS1003-9953%2810%2960243-5&partnerID=40&md5=87ce0fa83f1699e7cebae8c8ac3a2f1d id_number: 10.1016/S1003-9953(10)60243-5 full_text_status: none publication: Journal of Natural Gas Chemistry volume: 20 number: 6 pagerange: 659-663 refereed: TRUE issn: 10039953 citation: Ali, S. and Zabidi, N.A.M. and Subbarao, D. (2011) Development of niobium-promoted cobalt catalysts on carbon nanotubes for Fischer-Tropsch synthesis. Journal of Natural Gas Chemistry, 20 (6). pp. 659-663. ISSN 10039953