@article{scholars1850, year = {2011}, pages = {659--663}, journal = {Journal of Natural Gas Chemistry}, doi = {10.1016/S1003-9953(10)60243-5}, volume = {20}, note = {cited By 5}, number = {6}, title = {Development of niobium-promoted cobalt catalysts on carbon nanotubes for Fischer-Tropsch synthesis}, issn = {10039953}, author = {Ali, S. and Zabidi, N. A. M. and Subbarao, D.}, abstract = {Cobalt-based catalysts were prepared by a wet impregnation method on carbon nanotubes (CNTs) support and promoted with niobium. Samples were characterized by nitrogen adsorption, TEM, XRD, TPR, TPO and H 2-TPD. Addition of niobium increased the dispersion of cobalt but decreased the catalysts reducibility. Fischer-Tropsch synthesis (FTS) was carried out in a fixed-bed microreactor at 543 K, 1 atm and H 2/CO = 2 for 5 h. Addition of niobium enhanced the C 5+ hydrocarbons selectivity by 39 and reduced methane selectivity by 59. These effects were more pronounced for 0.04Nb/Co/CNTs catalyst, compared with those observed for other niobium compositions. {\^A}{\copyright} 2011 CAS/DICP. All rights reserved.}, keywords = {CNTs; Cobalt Catalyst; Cobalt-based catalysts; Fischer Tropsch; Fixed-bed; Micro-reactor; Nitrogen adsorption; Wet impregnation method; XRD, Carbon nanotubes; Catalysts; Cobalt; Gas adsorption; Methane; Niobium, Fischer-Tropsch synthesis}, url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-83455246790&doi=10.1016\%2fS1003-9953\%2810\%2960243-5&partnerID=40&md5=87ce0fa83f1699e7cebae8c8ac3a2f1d} }