eprintid: 1830
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/00/18/30
datestamp: 2023-11-09 15:50:00
lastmod: 2023-11-09 15:50:00
status_changed: 2023-11-09 15:41:26
type: article
metadata_visibility: show
creators_name: Ismail Hossain, M.
creators_name: Babaa, M.-R.
creators_name: El-Harbawi, M.
creators_name: Man, Z.
creators_name: Hefter, G.
creators_name: Yin, C.-Y.
title: Synthesis, characterization, physical properties, and cytotoxicities of 1-(6-hydroxyhexyl)-3-alkylimidazolium chloride ionic liquids
ispublished: pub
keywords: Alkylimidazolium; Dynamic viscosities; Empirical correlations; Imidazolium cation; Imidazolium-based ionic liquid; IR and NMR spectroscopy; Side chain lengths; Side-chains, Atmospheric pressure; Chain length; Chlorine compounds; Density of liquids; Ions; Light refraction; Nuclear magnetic resonance spectroscopy; Refractive index; Refractometers; Surface properties; Surface tension; Viscosity, Ionic liquids
note: cited By 20
abstract: Four hydroxyl-functionalized ionic liquids, 1-(6-hydroxyhexyl)-3- alkylimidazolium chlorides 6OHimCnCl; (n = 0, 1, 2, 4), have been synthesized from the appropriate imidazole precursors and characterized by IR and NMR spectroscopies and elemental analysis. Densities, dynamic viscosities, refractive indices, and surface tensions have been measured for each liquid as a function of temperature at atmospheric pressure and fitted using simple empirical correlation functions. Consistent with related imidazolium-based ionic liquids, an increase in the carbon side-chain length of the imidazolium cation was found to decrease the density and surface tension but increase the viscosity and refractive index. Cytotoxicities of the present liquids were found to decrease with increasing carbon side chain length and were broadly similar to those of other ionic liquids. © 2011 American Chemical Society.
date: 2011
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-80955164051&doi=10.1021%2fje200589f&partnerID=40&md5=6467f230478d213d0d4f7520984a6e6c
id_number: 10.1021/je200589f
full_text_status: none
publication: Journal of Chemical and Engineering Data
volume: 56
number: 11
pagerange: 4188-4193
refereed: TRUE
issn: 00219568
citation:   Ismail Hossain, M. and Babaa, M.-R. and El-Harbawi, M. and Man, Z. and Hefter, G. and Yin, C.-Y.  (2011) Synthesis, characterization, physical properties, and cytotoxicities of 1-(6-hydroxyhexyl)-3-alkylimidazolium chloride ionic liquids.  Journal of Chemical and Engineering Data, 56 (11).  pp. 4188-4193.  ISSN 00219568