eprintid: 18029
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/80/29
datestamp: 2024-06-04 14:10:07
lastmod: 2024-06-04 14:10:07
status_changed: 2024-06-04 14:01:08
type: article
metadata_visibility: show
creators_name: Chin, S.Y.
creators_name: Lim, S.F.
creators_name: Lau, K.K.
creators_name: Thangavel, M.
creators_name: Kamaruzaman, M.R.
title: Iron-Based Nanoparticles Oxygen Scavenger for Suppressing Heat-Stable Salts Formation in Amine
ispublished: pub
keywords: Cost effectiveness; Iron; Nanoparticles; Salts, Degraded products; Diethanolamine solutions; Heat stable salts; Iron-based; Iron-based nanoparticle; Methyldiethanolamine; Oxygen scavengers; Oxygen scavenging; Protonated; Salt formation, Dissolved oxygen
note: cited By 0
abstract: Heat-stable salts (HSS), which trigger excessing foaming in absorber, are formed when protonated methyl diethanolamine (MDEA) reacts with the more acidic degraded products in the presence of dissolved oxygen (DO). The aim is to suppress the HSS formation in MDEA solution inaugurally employing a hybrid iron-based nanoparticles (HINP) oxygen scavenger. It was discovered that the oxygen-scavenging performance of a more cost-effective 20 Fe/HZSM5 was one-fold higher than the 20 Fe/MCM-41. The former was verified for its superior structural properties. The Fe2+ on its surface first reacted with DO, preventing DO from oxidizing the MDEA. Consequently, the absence of hydroxyl radicals eliminated the potential of formic acid formation, hence suppressing the MDEA-acid HSS formation. © 2023 Wiley-VCH GmbH.
date: 2023
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85169930543&doi=10.1002%2fceat.202300081&partnerID=40&md5=650bf9df2fed296db595183884d50abc
id_number: 10.1002/ceat.202300081
full_text_status: none
publication: Chemical Engineering and Technology
volume: 46
number: 12
pagerange: 2670-2675
refereed: TRUE
citation:   Chin, S.Y. and Lim, S.F. and Lau, K.K. and Thangavel, M. and Kamaruzaman, M.R.  (2023) Iron-Based Nanoparticles Oxygen Scavenger for Suppressing Heat-Stable Salts Formation in Amine.  Chemical Engineering and Technology, 46 (12).  pp. 2670-2675.