%O cited By 10 %X Palm oil methyl ester is blended with diesel oil as a commercial diesel product in Malaysia, known as biodiesel B10. Biodiesel mixed with water proved to reduced simultaneously both the particulate matter and NOx during combustion. Emulsified biodiesel also caused a secondary atomization due to micro-explosion of the fuel droplets, which is beneficial in improving combustion efficiency. The main factors and events leading to micro-explosion for palm oil derived biodiesel emulsified fuel has yet to be made available in the open literature. Hence, this study aimed to visualize the droplet evolution to micro-explosion of single droplet when heated. A single droplet was placed on the hot surface of a hotplate maintained at 500 °C and the droplet evolution time leading to micro-explosion were capture using a high-speed camera. The study found that all samples of the emulsified fuels produced micro-explosions in four distinct stages. The droplet underwent from a homogenous emulsion, turning from milky color to being transparent during the separation stage, volume expansion during the bubble growth stage, intense coalescence and puffing stage and finally micro-explosion stage. Larger water particles size and higher hydrophilic-lipophilic balance values are the main factors that caused shorter time leading to micro-explosion of droplets. © 2021 THE AUTHORS %K Alternative fuels; Atomization; Combustion; Diesel engines; Drops; Emulsification; Explosions; High speed cameras; Palm oil, Diesel oil; Diesel products; Emulsified fuel; Malaysia; Micro explosion; Palm oil methyl esters; Particulate Matter; Puffing; Secondary atomization; Single droplet, Biodiesel %L scholars17903 %A S.M. Syed Masharuddin %A Z.A. Abdul Karim %A M.A. Meor Said %A N.H. Amran %A M.A. Ismael %D 2022 %N 1 %I Elsevier B.V. %P 541-547 %V 61 %R 10.1016/j.aej.2021.06.043 %J Alexandria Engineering Journal %T The evolution of a single droplet water-in-palm oil derived biodiesel emulsion leading to micro-explosion