%0 Journal Article
%@ 20734344
%A Hasanudin, N.
%A Abd Ghani, N.
%A Ab Rahim, A.H.
%A Azman, N.S.
%A Rosdi, N.A.
%A Masri, A.N.
%D 2022
%F scholars:17024
%I MDPI
%J Catalysts
%N 3
%R 10.3390/catal12030277
%T Optimization and Kinetic Studies on Biodiesel Conversion from Chlorella vulgaris Microalgae Using Pyrrolidinium-Based Ionic Liquids as a Catalyst
%U https://khub.utp.edu.my/scholars/17024/
%V 12
%X This study describes the potential conversion of dried microalgae. Chlorella vulgaris (C. vul-garis) into fatty acid methyl ester (FAME) using the direct transesterification (DT) method and using ionic liquids (ILs) as a catalyst. In this work, the performance of monocationic IL, namely 1-butyl-1-methylpyrrolidinium bromide (IL 1), and dicationic IL, namely 1,4-bis(1-methylpyrrolidinium-1-yl) butane dibromide (IL 2), as catalysts was compared for DT of C. vulgaris under microwave irradiation. The results revealed that IL 2 showed a better performance in catalyzing the DT reaction by producing 87.9 mg/g of FAME, while the use of IL 1 led to 74.3 mg/g of FAME under optimum conditions. The kinetic study for direct transesterification of C. vulgaris showed that the reaction followed a first order kinetic reaction where the activation energies were calculated to be 22.2499 kJ mol�1 and 22.0413 kJ mol�1 for IL 1 and IL 2, respectively. © 2022 by the authors. Licensee MDPI, Basel, Switzerland.
%Z cited By 1