<> "The repository administrator has not yet configured an RDF license."^^ . <> . . . "Hydrogen-rich syngas production from bi-reforming of greenhouse gases over zirconia modified Ni/MgO catalyst"^^ . "Bi-reforming of methane (BRM) is gaining an increase interest due to the critical requirements to mitigate global warming and provide alternative energy resources. However, there has been a serious challenge to the scale-up of the process to commercial production due to the catalyst deactivation. In the present study, the influence of ZrO2 modifications on the activity and stability of MgO-supported Ni catalyst in the BRM reaction was investigated. The ZrO2-MgO mixed oxide support was prepared by co-precipitation method with variation in the ZrO2 composition and subsequently impregnated with Ni. The characterization of the freshly prepared Ni/MgO and Ni/MgO-ZrO2 catalysts using N2 physisorption analysis, X-Ray Diffraction (XRD), FESEM, XPS, H2-TPR, and CO2-TPD techniques revealed suitable physicochemical properties for the BRM reaction. The Ni/MgO-ZrO2 catalysts showed an improved performance in the BRM reaction in terms of activity and stability compared to the Ni/MgO at 800°C and CH4, H2O, CO2 ratio of 3:2:1, respectively. The best performance was obtained using the Ni/15ZrO2-MgO for the BRM with CO2 and CH4 conversion of 81.5 and 82.5, respectively. The characterization of the spent Ni/MgO catalyst using Raman spectroscopy, FESEM, and High Resolution Transmission Electron Microscopy (HRTEM) analysis revealed the formation of amorphous carbon that could be responsible for its fast deactivation. © 2021 John Wiley & Sons Ltd."^^ . "2022" . . "46" . "3" . . "John Wiley and Sons Ltd"^^ . . . "International Journal of Energy Research"^^ . . . "0363907X" . . . . . . . . . . . . . . . . . . . . . . . . . "M."^^ . "Yusuf"^^ . "M. Yusuf"^^ . . "R."^^ . "Saidur"^^ . "R. Saidur"^^ . . "A.S."^^ . "Farooqi"^^ . "A.S. Farooqi"^^ . . "B.V."^^ . "Ayodele"^^ . "B.V. Ayodele"^^ . . "N.A.M."^^ . "Zabidi"^^ . "N.A.M. Zabidi"^^ . . "M.U."^^ . "Shahid"^^ . "M.U. Shahid"^^ . . "B."^^ . "Abdullah"^^ . "B. Abdullah"^^ . . . . . "HTML Summary of #16982 \n\nHydrogen-rich syngas production from bi-reforming of greenhouse gases over zirconia modified Ni/MgO catalyst\n\n" . "text/html" . .