@article{scholars16783, year = {2022}, title = {Elucidating the Effects of Reaction Time on the Physicochemical Characterization of Valorized Synthesized Alumina}, doi = {10.3390/ma15093046}, journal = {Materials}, volume = {15}, note = {cited By 1}, publisher = {MDPI}, number = {9}, keywords = {Corundum; Pore structure; Sols; Waste management; X ray diffraction, Aluminum waste; Aluminum waste can; Characterization; Malaysia; Metropolitan area; Physico-chemical characterization; Public health issues; Sol - Gel synthesis; Synthesised; Value added products, Aluminum oxide}, url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85129279512&doi=10.3390\%2fma15093046&partnerID=40&md5=f3d51b5e206243f6ea14c0e4c96ee009}, author = {Bin Mokaizh, A. A. and Shariffuddin, J. H. and Baarimah, A. O. and Al-Fakih, A. and Mohamed, A. and Baarimah, S. O. and Al-Mekhlafi, A.-B. A. and Alenezi, H. and Olalere, O. A. and Saeed, A. A. H.}, issn = {19961944}, abstract = {Aluminum waste-can management in Malaysia has recently become a serious environmental and public health issue, particularly in metropolitan areas. This has prompted the need to valorize these waste-cans into value-added products using the most economical and environmentally friendly techniques. In this study, the sol{\^a}??gel technique was used to synthesize high-quality alumina from the aluminum waste-cans collected. From this method, the observed peaks of the synthesized alumina were identified as diaspore ({\^I}{$\pm$}-AlO(OH)), boehmite ({\^I}3-AlO(OH)), aluminum oxide, or gamma-alumina ({\^I}3-Al2O3 ) crystalline structure and corundum. The morphological configuration, microstructure, and functional group properties of the synthesized alumina were evaluated. All the synthesized alumina exhibited a non-spherical shape and appeared to have hexagonal-like shape particles. Moreover, the XRD patterns of the synthesized alumina AL-6-30 and AL-12-30 exhibited a small angle (1{\^a}??10{\^a}?? ) with no XRD peak, which indicated a mesoporous pore structure with no long-range order. The overall results of {\^I}3-alumina synthesized from the aluminum waste-cans showed an optimal condition in producing a highly structured {\^I}3-alumina with excellent surface-area characteristics. The synthesized alumina exhibited stronger and highly crystalline functional characteristics almost comparable with the commercially available brands on the market. {\^A}{\copyright} 2022 by the authors. Licensee MDPI, Basel, Switzerland.} }