TY  - JOUR
AV  - none
TI  - Synergistic effects of catalytic co-pyrolysis Chlorella vulgaris and polyethylene mixtures using artificial neuron network: Thermodynamic and empirical kinetic analyses
ID  - scholars16714
KW  - Binary mixtures; Catalysts; Genetic algorithms; High density polyethylenes; Kinetic parameters; Lime; Neural networks; Pyrolysis; Thermogravimetric analysis; Zeolites
KW  -  Artificial neuron networks; Bi-functional; Catalytic pyrolysis; Chlorella vulgaris; Copyrolysis; Empirical model; Kinetic analysis; Kinetics parameter; Microalga chlorellum vulgari; ]+ catalyst
KW  -  Microalgae
N1  - cited By 25
N2  - The catalytic pyrolysis of Chlorella vulgaris, high-density polyethylene (Pure HDPE) and, their binary mixtures were conducted to analyse the kinetic and thermodynamic performances from 10 to 100 K/min. The kinetic parameters were computed by substituting the experimental and ANN predicted data into these iso-conversional equations and plotting linear plots. Among all the iso-conversional models, Flynn-Wall-Ozawa (FWO) model gave the best prediction for kinetic parameters with the lowest deviation error (2.28-12.76). The bifunctional HZSM-5/LS catalysts were found out to be the best catalysts among HZSM-5 zeolite, natural limestone (LS), and bifunctional HZSM-5/LS catalyst in co-pyrolysis of binary mixture of Chlorella vulgaris and HDPE, in which the Ea of the whole system was reduced from range 144.93-225.84 kJ/mol (without catalysts) to 75.37-76.90 kJ/mol. With the aid of artificial neuron network and genetic algorithm, an empirical model with a mean absolute percentage error (MAPE) of 51.59 was developed for tri-solid state degradation system. The developed empirical model is comparable to the thermogravimetry analysis (TGA) experimental values alongside the other empirical model proposed in literature © 2022 Elsevier Ltd.
IS  - 3
PB  - Elsevier Ltd
SN  - 22133437
Y1  - 2022///
VL  - 10
A1  - Yap, T.L.
A1  - Loy, A.C.M.
A1  - Chin, B.L.F.
A1  - Lim, J.Y.
A1  - Alhamzi, H.
A1  - Chai, Y.H.
A1  - Yiin, C.L.
A1  - Cheah, K.W.
A1  - Wee, M.X.J.
A1  - Lam, M.K.
A1  - Jawad, Z.A.
A1  - Yusup, S.
A1  - Lock, S.S.M.
JF  - Journal of Environmental Chemical Engineering
UR  - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85125755055&doi=10.1016%2fj.jece.2022.107391&partnerID=40&md5=a80dbff94aba18ebee678cde67296944
ER  -