TY  - JOUR
N2  - The metal-cations and non-metal anions mono-doped titanium dioxide (TiO2) systems have shown limited success as an efficient photocatalyst for various photocatalytic applications. Instead, the co-doping of TiO2with metal and non-metal dopants is transpired as an effective doping approach to reduce the wide bandgap of the TiO2and harvest a greater amount of the visible solar spectrum. Herein, a computational study was systematically performed to develop an efficient carbon-copper (C-Cu) co-doped TiO2anatase system and compared its optoelectronic characteristics with the copper (Cu) mono-doped TiO2system. The structural properties simulated with Perdew-Burke-Ernzerhof assisted generalized gradient approximation (GGA + PBE) whereas the electronic and optical properties with Hubbard's modified (GGA + U) approximation. The electronic band structure and density of states plots display reduced bandgap energy of 2.30 eV for the C-Cu co-doped TiO2anatase model in comparison to Cu mono-doped TiO2anatase model. Moreover, the absorption spectra display a redshift of the optical absorption edge up to 515 nm for the co-doped system. Overall, the DFT work provide clear insights and predictions that the C-Cu co-doped TiO2anatase model has an efficient bandgap narrowing with a significant redshift of the optical absorption edge in comparison to Cu mono-doped TiO2model. © 2022 Chemical Publishing Co.. All rights reserved.
IS  - 7
ID  - scholars16607
A1  - Ullah, F.
A1  - Mohamed, N.M.
A1  - Ghani, U.
A1  - Saheed, M.S.M.
JF  - Asian Journal of Chemistry
UR  - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85132339364&doi=10.14233%2fajchem.2022.23621&partnerID=40&md5=5d7e1e48355474762812b514cd4d03a4
VL  - 34
Y1  - 2022///
N1  - cited By 1
TI  - First Principle DFT + U Calculations for the Optoelectronic Properties of Cu and C-Cu co-doped TiO2Anatase Model
SP  - 1863
AV  - none
EP  - 1868
PB  - Asian Publication Corporation
SN  - 09707077
ER  -