%D 2022 %R 10.1021/acs.energyfuels.2c00310 %N 15 %O cited By 4 %J Energy and Fuels %L scholars16492 %K Brittleness; Carbon dioxide; Contact angle; Fracture mechanics; Hydraulic fracturing; Plasticity; Quartz; Reservoirs (water); Shale; Wetting, Brittleness index; Experimental assessment; Fluid interactions; Foam-fracturing fluids; Fracture initiation; Fracture initiation pressures; Fracture propagation; Initiation and propagation; Shale formation; Water sensitive, Fracturing fluids %X CO2foam fracturing fluid has received significant attention because of its versatility in water-sensitive formations. However, the mechanisms of hydraulic fracturing of shale reservoirs by CO2foam fracking fluid, in terms of fracture initiation and propagation remain unclear. In this paper, an experimental study was conducted to correlate the fluid interaction and fracture propagation in various shale formations having brittleness indices of 0.43, 0.50, and 0.74 to the rock-fracking fluid wettability. The shale wetting state in the presence of the CO2foam fracturing fluid was determined from contact angle measurements through the Krüss drop shape analyzer (DSA 100), and the hydraulic fracturing was conducted via a tri-axial fracking system. A specific concentration of polyacrylamide (500 ppm) is used as a drag-reducing agent and selected for the hydraulic fracturing experiments. CO2foam fracturing resulted in low fracture initiation pressure in the shale, having a high brittleness index of 0.74 BIm, and it remains the same at high temperatures. The length and aperture of the hydraulic fracture were then correlated with fracturing fluid-shale contact angles. The Mancos shale is sand-rich (with 21 wt calcite and 52 wt quartz), and it remained strongly water-wet on the interaction with the fracking fluid, and the net breakdown pressure was found to be lower in the fracturing tests of the Mancos shale. The Marcellus shale (with 31 wt calcite and 22 wt quartz) was intermediately wet (with a contact angle of 93.1°), whereas the Eagle Ford shale with high clay content (77 wt calcite and 11 wt quartz) was CO2-wet (with a contact angle of 109°) at 80 °C. Marcellus and Eagle Ford shales demonstrated higher fracture initiation pressures during the fracking experiments than the Mancos shale. The study suggests that fracking fluid-shale wettability has an essential role in the fracking of shale formations and should be considered in optimizing hydraulic fracturing fluid. © 2022 American Chemical Society. All rights reserved. %P 8288-8300 %T Experimental Assessment of Fracture Initiation and Wettability in Low and High Brittle Shales by CO2Foam Fracturing Fluids %I American Chemical Society %A J.A. Khan %A E. Padmanabhan %A I.U. Haq %A N. Yekeen %A M. Mumtaz %A S. Prajapati %V 36