TY - JOUR EP - 30809 SN - 03603199 PB - Elsevier Ltd TI - Sulfur enriched cobalt-based layered double hydroxides for oxygen evolution reactions SP - 30799 N1 - cited By 9 AV - none VL - 47 UR - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85116910891&doi=10.1016%2fj.ijhydene.2021.09.201&partnerID=40&md5=8a64c6352ad90960a4d1f5e5aa03b740 A1 - Ullah, S. A1 - Shamraiz, U. A1 - Elizbit A1 - Badshah, A. A1 - Raza, B. A1 - Farooqi, A.S. A1 - Tofil, H.M. A1 - Zeb, M.A. A1 - Alfantazi, A. JF - International Journal of Hydrogen Energy Y1 - 2022/// KW - Electrocatalysis; High resolution transmission electron microscopy; Oxygen; Positive ions; Sulfur; X ray photoelectron spectroscopy KW - Cation and anion substitution; Co-precipitation; Cobalt-based; High current densities; Layered Structures; Layered-double hydroxides; One-step methods; Simple++; Synthesised; Water oxidation KW - Cobalt compounds ID - scholars16475 N2 - Sulfur and zinc substituted Co(OH)2 is synthesized by a simple co-precipitation one-step method followed by solvothermal treatment for oxygen evolution reaction. The high-resolution X-ray photoelectron spectroscopy (XPS) and high-resolution transmission electron microscopy (HRTEM) demonstrates that the Zn and S substitution significantly stabilizes the layered structure and causes an increase in the electron density around the Co center. The role of both cation and anion substitution is evaluated to enhance the oxygen evolution reactions. This enhanced activity is due to the in-situ oxidation of divalent Co into trivalent Co, and partially due to the stabilization of the layered structure, as highlighted by PXRD and TEM analysis, the gap between the layers is slightly reduced from 7.8 à to 7.5 à , for Sâ??Znâ??Co(OH)2. The in-situ conversion of Co2+ to Co3+ during electrocatalysis improved the OER electrocatalysis. The structural and physical characterizations are performed via XRD, EDX, SEM, TEM, XPS, AFM and BET. © 2021 Hydrogen Energy Publications LLC IS - 72 ER -