eprintid: 16439 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/01/64/39 datestamp: 2023-12-19 03:22:58 lastmod: 2023-12-19 03:22:58 status_changed: 2023-12-19 03:06:15 type: article metadata_visibility: show creators_name: Yavari, S. creators_name: Kamyab, H. creators_name: Binti Abd Manan, T.S. creators_name: Chelliapan, S. creators_name: Asadpour, R. creators_name: Yavari, S. creators_name: Sapari, N.B. creators_name: Baloo, L. creators_name: Sidik, A.B.C. creators_name: Kirpichnikova, I. title: Bio-efficacy of imidazolinones in weed control in a tropical paddy soil amended with optimized agrowaste-derived biochars ispublished: pub keywords: Herbicides; Mixtures; Palm oil; Seed; Soils; Stabilization; Tropics; Weed control, Agro-wastes; Amended soil; Application rates; Biochar; Empty fruit bunches; Herbicide efficiency; Imazapic; Imazapyr; Imidazolinone; Rice husk biochar, Efficiency, charcoal; herbicide; imidazole derivative; imidazolinone derivative; unclassified drug; charcoal, biochar; black carbon; food waste; paddy field; soil amendment; weed control, agricultural waste; Article; biomass production; controlled study; Elaeis; fruit; germination; greenhouse; Malaysian; paddy field; paddy soil; plant growth; plant seed; rice husk; tropical forest; weed control; chemistry; Oryza; soil; soil pollutant; weed control, Charcoal; Herbicides; Oryza; Soil; Soil Pollutants; Weed Control note: cited By 14 abstract: Biochar is a black carbon sorbent that has the ability to stabilize organic substances in soil and, therefore, the potential to reduce their bio-availability. This sustainable material can be produced from locally-available agro wastes. The present study, for the first time, investigated the effects of biochars produced from oil palm empty fruit bunches (EFB) and rice husk (RH) on the efficiency of imazapic and imazapyr (two polar members of imidazolinone herbicides) as well as Onduty®, a mixture of them. It was executed in a Malaysian paddy field soil during a 30-day greenhouse experiment. The presence of optimized EFB and RH biochars in the heavy soil generally increases weed seeds germination and plants growth due to stabilization of the herbicides. The effect of EFB biochar was found higher than RH biochar having a higher affinity to the herbicides. An increase in the biochars application rates enhanced their effects as a soil modifier. Differences were more significant in the higher herbicides doses. Efficacies of all the herbicides were generally decreased in the biochar-amended soils. In the presence of 0.5 biochar in soil, the GR50 values for all herbicides were almost similar to biochar-free soil. In a 1.0 biochar-soil mixture, GR50 values of the herbicides increased by about 1.5 times. Bio-efficacies of the herbicides decreased by around 2.0 times as the biochar application rate enhanced to 2.0. The greatest GR50 values were obtained in the presence of 4.0 biochar in the soils and were about 7.0�8.5 folds, indicating the high capability of amended soil in the stabilization of the herbicides. The findings of this study can help to reduce imidazolinones� pollution and, in this way, prevent the threats of their residues to the environment. © 2022 Elsevier Ltd date: 2022 publisher: Elsevier Ltd official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85130585477&doi=10.1016%2fj.chemosphere.2022.134957&partnerID=40&md5=696cee5a9c9f86ab739e977e04938f6a id_number: 10.1016/j.chemosphere.2022.134957 full_text_status: none publication: Chemosphere volume: 303 refereed: TRUE issn: 00456535 citation: Yavari, S. and Kamyab, H. and Binti Abd Manan, T.S. and Chelliapan, S. and Asadpour, R. and Yavari, S. and Sapari, N.B. and Baloo, L. and Sidik, A.B.C. and Kirpichnikova, I. (2022) Bio-efficacy of imidazolinones in weed control in a tropical paddy soil amended with optimized agrowaste-derived biochars. Chemosphere, 303. ISSN 00456535