@article{scholars16397,
            year = {2022},
           title = {Co-Production of Methanol and Methyl Formate via Catalytic Hydrogenation of CO2 over Promoted Cu/ZnO Catalyst Supported on Al2O3 and SBA-15},
             doi = {10.3390/catal12091018},
         journal = {Catalysts},
          volume = {12},
            note = {cited By 1},
       publisher = {MDPI},
          number = {9},
          author = {Berahim, N. H. and Mohd Zabidi, N. A. and Suhaimi, N. A.},
             url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85138655382&doi=10.3390\%2fcatal12091018&partnerID=40&md5=5716fe7f2ea9ef30b4a6eb392432bd31},
        abstract = {Cu/ZnO catalysts promoted with Mn, Nb and Zr, in a 1:1:1 ration, and supported on Al2O3 (CZMNZA) and SBA-15 (CZMNZS) were synthesized using an impregnation method. The catalytic performance of methanol synthesis from CO2 hydrogenation was investigated in a fixed-bed reactor at 250 {\^A}oC, 22.5 bar, GHSV 10,800 mL/g{\^A}.h and H2/CO2 ratio of 3. The CZMNZA catalyst resulted in higher CO2 conversion and MeOH selectivity of 7.22 and 32.10, respectively, despite having a lower BET surface area and pore volume compared to CZMNZS. Methyl formate is the major product obtained over both types of catalysts. The CZMNZA is a promising catalyst for co-producing methanol and methyl formate via the CO2 hydrogenation reaction. {\^A}{\copyright} 2022 by the authors.},
            issn = {20734344}
}