eprintid: 16283 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/01/62/83 datestamp: 2023-12-19 03:22:49 lastmod: 2023-12-19 03:22:49 status_changed: 2023-12-19 03:05:58 type: article metadata_visibility: show creators_name: Tien Thanh, N. creators_name: Mostapha, M. creators_name: Lam, M.K. creators_name: Ishak, S. creators_name: Kanna Dasan, Y. creators_name: Lim, J.W. creators_name: Tan, I.S. creators_name: Lau, S.Y. creators_name: Chin, B.L.F. creators_name: Hadibarata, T. title: Fundamental understanding of in-situ transesterification of microalgae biomass to biodiesel: A critical review ispublished: pub keywords: Biodiesel; Biomass; Energy efficiency; Microorganisms; Reaction kinetics; Thermodynamics; Transesterification, Biodiesel production; Critical review; Energy efficient; In-situ transesterification; Micro-algae; Processing parameters; Reaction parameters; Situ transesterification; Techno-economics; Two-step process, Microalgae note: cited By 21 abstract: One-step in-situ transesterification has been recognized as an alternative approach to produce biodiesel from microalgae biomass. Based on technoeconomic perspective, in-situ transesterification of microalgae is more energy efficient than the conventional two-step process and thus economically competitive for biodiesel production. However, a comprehensive review on the effect of processing parameters towards conversion efficiency of microalgae biomass to biodiesel via in-situ transesterification is still lacking in the literature. Therefore, this review was intended to deliberate on fundamental understanding of this technology, including the effect of different reaction parameters towards biodiesel yield, technoeconomic impact of using wet paste microalgae, biodiesel composition profiles, and the state-of-the-art of the process. Besides, reaction kinetic and thermodynamics aspect of in-situ transesterification from microalgae were also discussed in detail. This review also provided in-depth information for process design and intensification under dedicated in-situ transesterification reaction condition for sustainable biodiesel production. Concurrently, research gaps in in-situ transesterification process was addressed for future study. © 2022 Elsevier Ltd date: 2022 publisher: Elsevier Ltd official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85138103443&doi=10.1016%2fj.enconman.2022.116212&partnerID=40&md5=726e6b34e8d748de615a344823d7dd8d id_number: 10.1016/j.enconman.2022.116212 full_text_status: none publication: Energy Conversion and Management volume: 270 refereed: TRUE issn: 01968904 citation: Tien Thanh, N. and Mostapha, M. and Lam, M.K. and Ishak, S. and Kanna Dasan, Y. and Lim, J.W. and Tan, I.S. and Lau, S.Y. and Chin, B.L.F. and Hadibarata, T. (2022) Fundamental understanding of in-situ transesterification of microalgae biomass to biodiesel: A critical review. Energy Conversion and Management, 270. ISSN 01968904