eprintid: 16275
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/62/75
datestamp: 2023-12-19 03:22:49
lastmod: 2023-12-19 03:22:49
status_changed: 2023-12-19 03:05:57
type: article
metadata_visibility: show
creators_name: Nawaz, R.
creators_name: Sahrin, N.T.
creators_name: Haider, S.
creators_name: Ullah, H.
creators_name: Junaid, M.
creators_name: Akhtar, M.S.
creators_name: Khan, S.
title: Photocatalytic performance of black titanium dioxide for phenolic compounds removal from oil refinery wastewater: nanoparticles vs nanowires
ispublished: pub
keywords: Effluents; Nanowires; Particle size; Phenols; Photocatalytic activity; Refining; Sols; Synthesis (chemical); TiO2 nanoparticles, Oil refineries; Oil refinery wastewater; Phenolic compound removal; Phenolic compounds; Phenols removal; Photo-catalytic; Photocatalytic performance; Photocatalytic remediation; Refinery wastewaters, Titanium dioxide
note: cited By 4
abstract: In this study, TiO2 nanoparticles (NPs) and TiO2 nanowires (NWs) were synthesized via modified sol�gel and hydrothermal methods, respectively. The TiO2 NPs and TiO2 NWs were characterized employing various analytical techniques. The performance of TiO2 NPs and TiO2 NWs was evaluated and compared for phenols� removal from model oil refinery wastewater under visible light irradiation. The TiO2 NPs and TiO2 NWs were pure anatase crystalline phases with average particle size of 10.17 nm and 6.82 nm and a narrow bandgap of 2.41 and 2.66 eV, respectively. 3D view surface plots confirm that the long-range atomic arrangement of the atom was intact, indicated by atomically flat surfaces. The recombination rate of electrons and holes was significantly lower in TiO2 NWs compared to TiO2 NPs. Both the samples were able to remove more than 90 of phenols from model oil refinery wastewater. Phenol removal from neutralized spent caustic took a longer time (300 min) compared to desalter effluent and tank water drain (<180 min). Phenol removal efficiency increased when TiO2 NPs and TiO2 NWs were employed combinedly. TiO2 NWs were highly stable, as suggested by their performance for photocatalytic removal of phenols after five consecutive cycles. © 2021, King Abdulaziz City for Science and Technology.
date: 2022
publisher: Springer Science and Business Media Deutschland GmbH
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85124284248&doi=10.1007%2fs13204-021-02240-5&partnerID=40&md5=c5803ebca4da5e66f32b2fcf1fc85bef
id_number: 10.1007/s13204-021-02240-5
full_text_status: none
publication: Applied Nanoscience (Switzerland)
volume: 12
number: 11
pagerange: 3499-3515
refereed: TRUE
issn: 21905509
citation:   Nawaz, R. and Sahrin, N.T. and Haider, S. and Ullah, H. and Junaid, M. and Akhtar, M.S. and Khan, S.  (2022) Photocatalytic performance of black titanium dioxide for phenolic compounds removal from oil refinery wastewater: nanoparticles vs nanowires.  Applied Nanoscience (Switzerland), 12 (11).  pp. 3499-3515.  ISSN 21905509