eprintid: 1619 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/00/16/19 datestamp: 2023-11-09 15:49:47 lastmod: 2023-11-09 15:49:47 status_changed: 2023-11-09 15:41:00 type: conference_item metadata_visibility: show creators_name: Hailegiorgis, S.M. creators_name: Mahadzir, S. creators_name: Subbarao, D. title: Reactive extraction of Jatropha curcas l assisted by phase transfer catalyst for the production of biodiesel ispublished: pub keywords: Biodiesel production; Central composite designs; Cetyl trimethyl ammonium bromides; Cetyltrimethylammonium bromide; Fatty acid methyl ester; In-situ; J. curcas; Jatropha curcas l; Model equations; Optimal conditions; Phase transfer catalysis; Phase transfer catalysts; Process Variables; Rate of reaction; Reactive extraction; Response Surface Methodology, Biodiesel; Mathematical models; Methanol; Optimization; Reaction rates; Solubility; Sustainable development; Transesterification; Vegetable oils, Innovation note: cited By 2; Conference of 3rd National Postgraduate Conference - Energy and Sustainability: Exploring the Innovative Minds, NPC 2011 ; Conference Date: 19 September 2011 Through 20 September 2011; Conference Code:88531 abstract: Transesterification is a very slow reaction due to limited solubility of alcohol in vegetable oils that strongly affect the reaction rate. Application of phase transfer catalyst (PTC) can be advantageous to improve the solubility of alcohol in oils and increase the rate of reaction. Use of cetyltrimethylammonium bromide (CTMAB) as a PTC on in-situ transesterification of J. curcas l. with alkaline methanol was investigated. Response surface methodology (RSM) was used to statistically evaluate and optimize the in situ transesterification method of biodiesel production. The effects of process variables were investigated using 2 5 factorial and central composite design (CCD) technique. Mathematical model was developed to predict the yield of fatty acid methyl esters (FAME). After optimizing the process variables using the model equation, FAME yield (88.25wt ) was predicted and compared with the experimental yield (89.3 ± 0.7wt ) obtained at optimal condition. There is a good agreement between the predicted value and the experimental result. © 2011 IEEE. date: 2011 official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84857089803&doi=10.1109%2fNatPC.2011.6136248&partnerID=40&md5=cbcb8c698addad380309d5fd4911556b id_number: 10.1109/NatPC.2011.6136248 full_text_status: none publication: 2011 National Postgraduate Conference - Energy and Sustainability: Exploring the Innovative Minds, NPC 2011 place_of_pub: Perak refereed: TRUE isbn: 9781457718847 citation: Hailegiorgis, S.M. and Mahadzir, S. and Subbarao, D. (2011) Reactive extraction of Jatropha curcas l assisted by phase transfer catalyst for the production of biodiesel. In: UNSPECIFIED.