relation: https://khub.utp.edu.my/scholars/16144/
title: Synthesis of ZIF-8 tubular membrane via solvent evaporation seeding coupled with microwave assisted heating method for separation of small molecule gases
creator: Suhaimi, N.H.
creator: Yeong, Y.F.
creator: Abdul Aziz, H.N.
creator: Lai, L.S.
description: In this work, we systematically study the performance of tubular ZIF-8 membranes in the separation of small molecules including H2, CO2, N2 and CH4. The tubular ZIF-8 membranes were synthesized on α-alumina support via novel dual approach known as solvent evaporation seeding coupled with microwave assisted growth. The durations for the growth of the seed layer through solvent evaporation and membrane layer via microwave heating were varied. The crystallinity and morphology of the resultant membranes were evaluated by using XRD, SEM and IFM analyses. The performance of the resultant tubular ZIF-8 membranes was assessed for small molecule gases permeation at various pressures and temperatures. Highest flux ranging from 0.02 to 0.61 mol/m2s were obtained for gases CO2, CH4, N2, and H2 at feed pressure of 10 bar, whereas highest ideal selectivity of 12.4, 9.3 and 6.9 were obtained for H2/CH4, CO2/CH4, N2/CH4, respectively, at feed pressure of 10 bar and temperature of 30 °C. This work reveals that the tubular ZIF-8 membrane can be synthesized via a feasible and reproducible solvent evaporation seeding coupled with microwave assisted growth method, which can be further explored for the upscaling of the ZIF-8 tubular membrane in pilot scale for gas separation application. © 2022 Elsevier Ltd
publisher: Elsevier Ltd
date: 2022
type: Article
type: PeerReviewed
identifier:   Suhaimi, N.H. and Yeong, Y.F. and Abdul Aziz, H.N. and Lai, L.S.  (2022) Synthesis of ZIF-8 tubular membrane via solvent evaporation seeding coupled with microwave assisted heating method for separation of small molecule gases.  Chemosphere, 308.   ISSN 00456535     
relation: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85137278119&doi=10.1016%2fj.chemosphere.2022.136167&partnerID=40&md5=6478c87a3a80e4000ca162be01fe5c55
relation: 10.1016/j.chemosphere.2022.136167
identifier: 10.1016/j.chemosphere.2022.136167