eprintid: 16130
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/61/30
datestamp: 2023-12-19 03:22:41
lastmod: 2023-12-19 03:22:41
status_changed: 2023-12-19 03:05:41
type: article
metadata_visibility: show
creators_name: Shokouhi, M.
creators_name: Vahidi, M.
creators_name: Mehrabi, M.
creators_name: Zhaleh Rajabi, E.
creators_name: Nakhaei Pour, A.
title: Solubility of Hydrogen Sulfide in Butanols: Experimental, Modeling, and Molecular Interpretation
ispublished: pub
note: cited By 0
abstract: The solubility of hydrogen sulfide in 1-butanol, 2-butanol and tertiary butanol was investigated at temperature from 313.15 to 353.15 K and pressures up to 2.3 MPa. The results show that the H2S solubility in these three isomers at low pressure is comparable and at higher pressures, the H2S solubility increase reflects steric effects, which increase in the order tertiary butyl alcohol > secondary butyl alcohol > normal butyl alcohol. The results were modeled by Peng�Robinson�Stryjek�Vera (PRSV) equation of state and extended Henry�s law as well; thereby, the fugacity coefficients at operational conditions and Henry's law constants of H2S solubility associated with solution enthalpy and entropy at infinite dilution were obtained and the variation of solubility was interpreted in terms of the variation of thermodynamic properties (enthalpy and entropy). The results of the two models are in good agreement in comparison with experimental data with average relative deviations of 2.5, 2.86, and 2.98 for 1-butanol, 2-butanol, and tertiary butanol, respectively, for PRSV EoS and 1.55, 1.51, and 2.41 for extended Henry�s law. © 2022, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.
date: 2022
publisher: Springer
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85139987707&doi=10.1007%2fs10953-022-01207-6&partnerID=40&md5=8f4c2faad1d947443dd42c073f6c6e87
id_number: 10.1007/s10953-022-01207-6
full_text_status: none
publication: Journal of Solution Chemistry
volume: 51
number: 12
pagerange: 1522-1539
refereed: TRUE
issn: 00959782
citation:   Shokouhi, M. and Vahidi, M. and Mehrabi, M. and Zhaleh Rajabi, E. and Nakhaei Pour, A.  (2022) Solubility of Hydrogen Sulfide in Butanols: Experimental, Modeling, and Molecular Interpretation.  Journal of Solution Chemistry, 51 (12).  pp. 1522-1539.  ISSN 00959782