eprintid: 15799 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/01/57/99 datestamp: 2023-11-10 03:30:25 lastmod: 2023-11-10 03:30:25 status_changed: 2023-11-10 02:00:26 type: article metadata_visibility: show creators_name: Isiyaka, H.A. creators_name: Ramli, A. creators_name: Jumbri, K. creators_name: Sambudi, N.S. creators_name: Zango, Z.U. creators_name: Saad, B. title: Adsorption and Artificial Neural Network Modelling of Metolachlor Removal by MIL-53(Al) Metal-Organic Framework ispublished: pub keywords: Chemicals removal (water treatment); Field emission microscopes; Forecasting; Metal-Organic Frameworks; Organometallics; Scanning electron microscopy, Accurate prediction; Aqueous medium; Effective materials; Equilibration time; Field emission scanning electron microscopy; Porous adsorbent; Prediction techniques; Removal efficiencies, Neural networks note: cited By 0; Conference of 2nd International Conference on Innovative Technology, Engineering and Sciences, iCITES 2020 ; Conference Date: 22 December 2020 Through 22 December 2020; Conference Code:256319 abstract: This study investigates the removal and prediction of metolachlor from aqueous medium using advanced prediction technique and porous adsorbent material (metal-organic framework (MOF)). The powdered X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), and Brunauer, Emmett and Teller (BET) were used to characterize the synthesized MOF. High removal efficiency (97.75) was recorded within short time (30 min) using only 10 mg of the MOF. The variation in the pH and concentration were also studied to understand the adsorption. The experimental data set for the training and validation were designed and predicted using the model of artificial neural network (ANN). The ANN model gave accurate prediction for training (R2 = 0.998; R2adj = 0.991 and RMSE = 0.311) and validation (R2 = 0.996; R2adj = 0.991 and RMSE = 0.441) at node five. The porous nature of the adsorbent (1104 m2 gâ��1), fast equilibration time, removal and accurate ANN prediction makes this MOF an effective material for remediating recalcitrant pollutants. © 2021, The Author(s), under exclusive license to Springer Nature Switzerland AG. date: 2021 publisher: Springer Science and Business Media Deutschland GmbH official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85104477231&doi=10.1007%2f978-3-030-70917-4_24&partnerID=40&md5=79eb87077fb4063588ce111d47d5b854 id_number: 10.1007/978-3-030-70917-4₂₄ full_text_status: none publication: Advances in Intelligent Systems and Computing volume: 1350 A pagerange: 245-255 refereed: TRUE isbn: 9783030709167 issn: 21945357 citation: Isiyaka, H.A. and Ramli, A. and Jumbri, K. and Sambudi, N.S. and Zango, Z.U. and Saad, B. (2021) Adsorption and Artificial Neural Network Modelling of Metolachlor Removal by MIL-53(Al) Metal-Organic Framework. Advances in Intelligent Systems and Computing, 1350 A. pp. 245-255. ISSN 21945357