eprintid: 15756 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/01/57/56 datestamp: 2023-11-10 03:30:23 lastmod: 2023-11-10 03:30:23 status_changed: 2023-11-10 02:00:19 type: article metadata_visibility: show creators_name: Almohamadi, H. creators_name: Aljabri, A. creators_name: Mahmoud, E.R.I. creators_name: Khan, S.Z. creators_name: Aljohani, M.S. creators_name: Shamsuddin, R. title: Catalytic pyrolysis of municipal solid waste: Effects of pyrolysis parameters ispublished: pub keywords: Alumina; Aluminum oxide; Catalyst activity; Catalyst supports; Global warming; Liquids; Magnesia; Municipal solid waste; Waste management, Active carbon; Bio-oils; Catalytic pyrolysis; CH 4; Deoxygenations; Gas yields; Liquid yield; Noncatalytic pyrolysis; Pyrolysis parameters; ]+ catalyst, Pyrolysis note: cited By 2 abstract: Burning municipal solid waste (MSW) increases CO2, CH4, and SO2 emissions, leading to an increase in global warming, encouraging governments and researchers to search for alternatives. The pyrolysis process converts MSW to oil, gas, and char. This study investigated catalytic and noncatalytic pyrolysis of MSW to produce oil using MgO-based catalysts. The reaction temperature, catalyst loading, and catalyst support were evaluated. Magnesium oxide was supported on active carbon (AC) and Al2O3 to assess the role of support in MgO catalyst activity. The liquid yields varied from 30 to 54 wt based on the experimental conditions. For the noncatalytic pyrolysis experiment, the highest liquid yield was 54 wt at 500 °C. The results revealed that adding MgO, MgO/Al2O3, and MgO/AC declines the liquid yield and increases the gas yield. The catalysts exhibited significant deoxygenation activity, which enhances the quality of the pyrolysis oil and increases the heating value of the bio-oil. Of the catalysts that had high deoxygenation activity, MgO/AC had the highest relative yield. The loading of MgO/AC varied from 5 to 30 wt of feed to the pyrolysis reactor. As the catalyst load increases, the liquid yield declines, while the gas and char yields increase. Copyright © 2021 by Authors, Published by BCREC Group. date: 2021 publisher: Diponegoro University official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85106495435&doi=10.9767%2fbcrec.16.2.10499.342-352&partnerID=40&md5=dbe9664c8e8724074e8ed2ae4a1eb462 id_number: 10.9767/bcrec.16.2.10499.342-352 full_text_status: none publication: Bulletin of Chemical Reaction Engineering and Catalysis volume: 16 number: 2 pagerange: 342-352 refereed: TRUE issn: 19782993 citation: Almohamadi, H. and Aljabri, A. and Mahmoud, E.R.I. and Khan, S.Z. and Aljohani, M.S. and Shamsuddin, R. (2021) Catalytic pyrolysis of municipal solid waste: Effects of pyrolysis parameters. Bulletin of Chemical Reaction Engineering and Catalysis, 16 (2). pp. 342-352. ISSN 19782993