TY  - JOUR
N2  - This study reveals that the effect of anion structures on solvent-solute interactions by analysis of sophisticated thermophysical properties of ionic liquids (ILs) with molecular solvent. Three imidazolium based ILs (1-octyl-3-methylimidazolium) OmimNTf2, OmimPF6 and OmimSCN were synthesized, characterized and measured the thermophysical properties such as density (Ï?) sound speed (u) and viscosity (η) of all ILs with DMF as solvent for binary mixture at various conditions. Furthermore, various derived thermophysical properties (Formula presented.), κs,Φ, (Formula presented.) and ηr, were calculated from experimental data. The type of interactions such as IL-IL or IL-solvent or solvent-solvent are occurred among the component molecules were estimated from the empirical parameters and COSMOâ??Rs computational study. The obtained results show that the size of anion is governing the volumetric, acoustic and viscometric properties of the studied ILs with DMF. © 2021 Wiley-VCH GmbH
IS  - 12
ID  - scholars15086
JF  - ChemistrySelect
A1  - Losetty, V.
A1  - Hazarathaiah Yadav, C.
A1  - Devi Wilfred, C.
A1  - Gardas, R.L.
UR  - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85103355880&doi=10.1002%2fslct.202004769&partnerID=40&md5=9d65e98d9d5f5b6adbee1bbf2939f203
VL  - 6
Y1  - 2021///
N1  - cited By 2
TI  - Investigation of Anion Structural Effects on Solute-Solvent Interactions of Ionic Liquids with DMF by Volumetric, Acoustic, Viscometric Properties and COSMO-RS Calculations
SP  - 2994
AV  - none
EP  - 3005
PB  - John Wiley and Sons Inc
SN  - 23656549
ER  -