eprintid: 15020
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/50/20
datestamp: 2023-11-10 03:29:37
lastmod: 2023-11-10 03:29:37
status_changed: 2023-11-10 01:58:26
type: article
metadata_visibility: show
creators_name: Khaidzir, S.
creators_name: Masri, A.N.
creators_name: Ruslan, M.S.H.
creators_name: Abdul Mutalib, M.I.
title: Ultrasonic-Assisted Technique as a Novel Method for Removal of Naphthenic Acid from Model Oil Using Piperidinium-Based Ionic Liquids
ispublished: pub
note: cited By 2
abstract: In this study, piperidinium-based ionic liquids (IL) containing trifluoromethanesulfonate, phenolate, and dicyanamide anions were synthesized. Using the ILs, extraction of naphthenic acid from highly acidic oil with a total acid number (TAN) of 1.44 was studied. Two agitation techniques have been implemented for the extraction process, which were mechanical stirring and ultrasonic-assisted irradiation. 1-Butyl-1-methylpiperidinium phenolate BMPiPhe showed the best potential in extracting naphthenic acid from oil, with complete removal of naphthenic acid with IL-to-oil ratios of 0.010 and 0.0025 for the mechanical stirring method and the ultrasonic-assisted method, respectively. Ultrasonic-assisted extraction process shows very good potential in enhancing the extraction efficiency of naphthenic acid. Optimization and study on the effects of ultrasonic parameters, namely, IL-to-oil ratio, ultrasonic amplitude, and time, were studied through response surface methodology (RSM). Using BMPiPhe, the optimum conditions obtained are IL-to-oil ratio of 0.03, 53.91% of amplitude, and 4.29 min of extraction time. Under these optimum conditions, 100% removal of naphthenic acid was achieved. © 2021 The Authors. Published by American Chemical Society.
date: 2021
publisher: American Chemical Society
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85104943207&doi=10.1021%2facsomega.1c00189&partnerID=40&md5=b03a7a3e858b3a3c15e8f77e7d2deaf9
id_number: 10.1021/acsomega.1c00189
full_text_status: none
publication: ACS Omega
volume: 6
number: 14
pagerange: 9629-9637
refereed: TRUE
issn: 24701343
citation:   Khaidzir, S. and Masri, A.N. and Ruslan, M.S.H. and Abdul Mutalib, M.I.  (2021) Ultrasonic-Assisted Technique as a Novel Method for Removal of Naphthenic Acid from Model Oil Using Piperidinium-Based Ionic Liquids.  ACS Omega, 6 (14).  pp. 9629-9637.  ISSN 24701343