eprintid: 14925
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/49/25
datestamp: 2023-11-10 03:29:31
lastmod: 2023-11-10 03:29:31
status_changed: 2023-11-10 01:58:11
type: conference_item
metadata_visibility: show
creators_name: Wahab, W.R.A.
creators_name: Yusup, S.
title: Kinetics, isotherm and thermodynamic modeling of liquid phase saponin sorption in soils.
ispublished: pub
keywords: Clay; Energy conservation; Isotherms; Kinetics; pH; Sand; Temperature, Dubinin-Radushkevich; Effects of temperature; Equilibrium isotherms; Intra-particle diffusion; Pseudo second order; Rate-limiting steps; Thermodynamic model; Thermodynamic studies, Physisorption
note: cited By 2; Conference of 1st International Conference on Biomass Utilization and Sustainable Energy 2020, ICoBiomasSE 2020 ; Conference Date: 15 December 2020 Through 16 December 2020; Conference Code:169103
abstract: The sorption behavior of saponin onto clay, paddy, silty loam and sandy soil was thoroughly evaluated in this study. The adsorption kinetic, isotherm and thermodynamic were conducted in batch analysis. Pseudo-first order, pseudo-second order and Elovich kinetic models were applied to evaluate the kinetics of the adsorption. Based on the models, the adsorption of saponin onto soils were mostly governed by physisorption while chemisorption also plays a role in the adsorption process in clay and paddy soil. Mechanism of adsorption was determined by adopting the intraparticle diffusion and Boyd models. The two models concluded that intraparticle diffusion is not the rate-limiting step in saponin uptake in all four soil types. Equilibrium isotherm was evaluated by using Langmuir, Freundlich and Dubinin-Radushkevich isotherm models. The data obeys both Langmuir and Freundlich model, however, Langmuir model tends to overestimate the qe value of the given soil. Clay soil showed highest maximum adsorption, followed by paddy, silty loam and sandy soil. Effects of temperature variation is minimal while variation in pH value was significant where optimum adsorption was achieved at near-neutral pH range. The thermodynamic study showed that the adsorption process was exothermic and spontaneous. © 2021 Institute of Physics Publishing. All rights reserved.
date: 2021
publisher: IOP Publishing Ltd
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85107121802&doi=10.1088%2f1755-1315%2f765%2f1%2f012111&partnerID=40&md5=1ecd2a56e1d8457a65b3dd3419e33b70
id_number: 10.1088/1755-1315/765/1/012111
full_text_status: none
publication: IOP Conference Series: Earth and Environmental Science
volume: 765
number: 1
refereed: TRUE
issn: 17551307
citation:   Wahab, W.R.A. and Yusup, S.  (2021) Kinetics, isotherm and thermodynamic modeling of liquid phase saponin sorption in soils.  In: UNSPECIFIED.