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primary topic: Viscosity and Ionic Conductivity of Imidazolium based Ionic Liquids bearing Triiodide Anion

Viscosity and Ionic Conductivity of Imidazolium based Ionic Liquids bearing Triiodide Anion
type: AcademicArticle
type: Article
abstract: In the electrolyte application for dye sensitized solar cells, utilization of ionic liquids is getting the highlights to replace volatile organic solvent thanks to their low volatility, thermal and electrochemical stability. The iodide/triiodide redox electrolyte is the preferred choice for this application, hence numerous iodide-based ionic liquids have been explored and reported. On the contrary, the transport properties of triiodide based ionic liquid is often lack of reporting despite of having an equal influence on the overall viscosity and ionic conductivity of the electrolyte. In this study, three alkylimidazolium triiodide ionic liquids were synthesized from the respective alkylimidazolium iodide ionic liquids precursors and their physicochemical and conductivity properties are reported. 1H NMR analysis showed a slight shifting of position of the resonances of triiodide based alkylimidazolium ionic liquids as compared to their precursors due to less electronegativity nature of triiodide anion. The formation of triiodide-based imidazolium ILs have dramatically altered the transport properties in which the ionic liquids obtained are of low viscosity and high ionic conductivity. © The Authors, published by EDP Sciences. This is an open access article distributed under the terms of the Creative Commons Attribution License 4.0 (http://creativecommons.org/licenses/by/4.0/)
date: 2021
volume: 287
is part of: E3S Web of Conferences
status: peerReviewed
status: published
author list: authors
type: EPrint
type: ConferenceItemEPrint
is part of: repository

EDP Sciences
type: Organization

E3S Web of Conferences
type: Collection
issn: 25550403

W.Z.N. Yahya
type: Person
given name: W.Z.N.
family name: Yahya

R.A.A. Talip
type: Person
given name: R.A.A.
family name: Talip

M.A. Bustam
type: Person
given name: M.A.
family name: Bustam

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primary topic: Viscosity and Ionic Conductivity of Imidazolium based Ionic Liquids bearing Triiodide Anion