TY - JOUR Y1 - 2021/// JF - International Journal of Hydrogen Energy A1 - Inayat, A. A1 - Khan, Z. A1 - Aslam, M. A1 - Shahbaz, M. A1 - Ahmad, M.M. A1 - Abdul Mutalib, M.I. A1 - Yusup, S. UR - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85098175897&doi=10.1016%2fj.ijhydene.2020.12.008&partnerID=40&md5=e62fc3960f971323a97f06a13a535e04 VL - 46 N2 - The generation of hydrogen-enriched synthesis gas from catalytic steam gasification of biomass with in-situ CO2 capture utilizing CaO has a high perspective as clean energy fuels. The present study focused on the process modeling of catalytic steam gasification of biomass using palm empty fruit bunch (EFB) as biomass for hydrogen generation through experimental work. Experiment work has been carried out using a fluidized bed gasifier on a bench-scale plant. The established model integrates the kinetics of EFB catalytic steam gasification reactions, in-situ capturing of CO2, mass and energy balance calculations. Chemical reaction constants have been calculated via the parameters fitting optimization approach. The influence of operating parameters, mainly temperature, steam to biomass, and sorbent to biomass ratio, was investigated for the hydrogen purity and yield through the experimental study and developed model. The results predicted approximately 75 vol of the hydrogen purity in the product gas composition. The maximum H2 yield produced from the gasifier was 127 gH2/kg of EFB via experimental setup. The increase in both steam to biomass ratio and temperature enhanced the production of hydrogen gas. Comparing the results with already published literature showed that the current system enables to produce a high amount of hydrogen from EFB. © 2020 Hydrogen Energy Publications LLC IS - 59 ID - scholars14565 KW - Biomass; Calcium oxide; Carbon dioxide; Fluidized beds; Gas generators; Gas industry; Gasification; Hydrogen fuels; Steam KW - Catalytic steam gasifications; Enhanced hydrogen productions; Fluidized bed gasifiers; Hydrogen generations; Mass and energy balance; Operating parameters; Optimization approach; Production of hydrogen KW - Hydrogen production PB - Elsevier Ltd SN - 03603199 EP - 30591 AV - none N1 - cited By 20 TI - Integrated adsorption steam gasification for enhanced hydrogen production from palm waste at bench scale plant SP - 30581 ER -