eprintid: 14428 rev_number: 2 eprint_status: archive userid: 1 dir: disk0/00/01/44/28 datestamp: 2023-11-10 03:29:00 lastmod: 2023-11-10 03:29:00 status_changed: 2023-11-10 01:56:53 type: article metadata_visibility: show creators_name: Nugraha, M.W. creators_name: Wirzal, M.D.H. creators_name: Ali, F. creators_name: Roza, L. creators_name: Sambudi, N.S. title: Electrospun polylactic acid/ tungsten oxide/ amino-functionalized carbon quantum dots (PLA/WO3/N-CQDs) fibers for oil/water separation and photocatalytic decolorization ispublished: pub keywords: Adsorption; Aromatic compounds; Contact angle; Durability; Fibers; Health risks; Hexane; Morphology; Nanocrystals; Semiconductor quantum dots; Surface morphology; Tungsten compounds; Wastewater treatment; Water absorption, Carbon quantum dots; Electrospuns; Fiber preparation; Functionalized; N-Hexane; Oil/water separation; Photocatalytic decolorization; Porous fibers; Separation performance; Tungsten oxide, Separation note: cited By 14 abstract: Oily wastewater generated from various industrial processes and oil spillages is a massive threat to the environment and human health. Hence, it is essential to develop novel material for practical oil/water separation and recovery. By incorporating WO3 (tungsten oxide)/ N-CQDs (amino-functionalized carbon quantum dots) into the matrix of polymer, the alteration of wettability behavior of electrospun PLA fiber is reported in this present work. The modified PLA/WO3/N-CQDs fibers shows a significantly enhanced hydrophobicity of the fibers while maintaining surface super-oleophilicity. These behaviors are achieved by modifying the surface contact angle and surface morphology of the composite PLA fiber using WO3/N-CQDs as filler. The PLA/WO3/N-CQDs EDA fiber exhibits the highest water contact angle (WCA) at 132.37º, oil absorption capacity at 35.752 g/g for n-hexane, oil separation performance at 8,326.048 L m�2 h�1 for n-hexane and 11,961.364 L m�2 h�1 for n-heptane, and decolorization of methylene blue (MB) at 91.80. Additionally, the PLA/WO3/N-CQDs EDA fiber demonstrated an excellent separation performance and durability after ten times cyclic separation performance test. This present study contributes to a potential application in the field of oily wastewater treatment. © 2021 Elsevier Ltd date: 2021 publisher: Elsevier Ltd official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85110038048&doi=10.1016%2fj.jece.2021.106033&partnerID=40&md5=f62113a611c8e5b1f6adc7c11c42c75c id_number: 10.1016/j.jece.2021.106033 full_text_status: none publication: Journal of Environmental Chemical Engineering volume: 9 number: 5 refereed: TRUE issn: 22133437 citation: Nugraha, M.W. and Wirzal, M.D.H. and Ali, F. and Roza, L. and Sambudi, N.S. (2021) Electrospun polylactic acid/ tungsten oxide/ amino-functionalized carbon quantum dots (PLA/WO3/N-CQDs) fibers for oil/water separation and photocatalytic decolorization. Journal of Environmental Chemical Engineering, 9 (5). ISSN 22133437