eprintid: 14248
rev_number: 2
eprint_status: archive
userid: 1
dir: disk0/00/01/42/48
datestamp: 2023-11-10 03:28:49
lastmod: 2023-11-10 03:28:49
status_changed: 2023-11-10 01:56:25
type: article
metadata_visibility: show
creators_name: Rehman, A.N.
creators_name: Bavoh, C.B.
creators_name: Pendyala, R.
creators_name: Lal, B.
title: Research Advances, Maturation, and Challenges of Hydrate-Based CO2Sequestration in Porous Media
ispublished: pub
keywords: Behavioral research; Carbon capture; Gas hydrates; Gas permeability; Global warming; Hydration; Mass transfer; Particle size; Porous materials; Sustainable development, Carbon capture and sequestrations; CO2 hydrates; CO2 storage; Hydrate formation; Phase behavior; Porous medium; Research advances; Research challenges; Safe storage; Storage capacity, Carbon dioxide
note: cited By 21
abstract: Hydrate-based CO2 storage/sequestration (HBCS) technique could potentially fulfill the mandate of the Sustainable Development Goal (SDG) 13 toward efficient and safe storage of CO2 through successful lab-scale experimentation in overcoming the existing storage capacity challenges. In this article, we carefully reviewed and discussed the reported fundamental lab-scale experimental attempts to successfully store CO2 as hydrate in sediments. The CO2 hydrate formation thermodynamics, kinetics, and mechanism insights in porous media are critically discussed to reveal the state of the art and the current challenges facing the implementation of the HBCS technique and provide guidelines and pathways toward a high CO2 storage capacity. In addition, factors affecting CO2 hydrate formation and hydrate formation mechanisms in various types of porous media are discussed. Factors that mainly control the CO2 storage capacity in porous media are driving force, porosity, capillary effect, gas and liquid permeability, particle size, and surface area. However, mass transfer limitation, potential storage site, CO2 transportation, CO2 injection technique, cost, environmental constraints, and CO2 stability are the main challenges toward the technological readiness of the HBCS. The findings in this work provide useful guidelines and pathways which could lead to an increase in CO2 storage capacity as hydrate for cleaner earth in the future. ©
date: 2021
publisher: American Chemical Society
official_url: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85119065623&doi=10.1021%2facssuschemeng.1c05423&partnerID=40&md5=1725b220ab128832ab62f392932f9e58
id_number: 10.1021/acssuschemeng.1c05423
full_text_status: none
publication: ACS Sustainable Chemistry and Engineering
volume: 9
number: 45
pagerange: 15075-15108
refereed: TRUE
issn: 21680485
citation:   Rehman, A.N. and Bavoh, C.B. and Pendyala, R. and Lal, B.  (2021) Research Advances, Maturation, and Challenges of Hydrate-Based CO2Sequestration in Porous Media.  ACS Sustainable Chemistry and Engineering, 9 (45).  pp. 15075-15108.  ISSN 21680485