@article{scholars14057, volume = {297}, note = {cited By 5}, year = {2020}, doi = {10.1016/j.molliq.2019.111843}, publisher = {Elsevier B.V.}, journal = {Journal of Molecular Liquids}, title = {Synthesis, thermophysical properties and CO2 sorption of imidazolium, thiazolium, iminium and morpholinium-based protic ionic liquids paired with 2-acrylamido-2-methyl-1-propanesulfonate anion}, url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85075503485&doi=10.1016\%2fj.molliq.2019.111843&partnerID=40&md5=6b4f2643907723b1e0cd92ef959f0477}, keywords = {Carbon dioxide; Ionic liquids; Physicochemical properties; Refractive index; Temperature distribution; Viscosity, AMPS; CO2 sorption; Henry's constants; Ionic liquid (ils); Protic ionic liquids; Structure activity relationships; Structure-activity relation; Temperature dependence, Density of liquids}, abstract = {The present study aims to investigate the temperature dependence of the physicochemical properties of four cations (namely 2-chloro-1,3-dimethylimidazolium diMeim, 3-benzyl-5-(2-hydroxyethyl)-4-thiazolium bnthia, (chloromethylene)dimethyl iminium diMeimi and morpholinium mrph) paired with common 2-acrylamido-2methyl-1-propanesulfonate AMPS anion. The density and viscosity of the resulting ionic liquids (ILs) were measured within temperature range of (293.15{\^a}??363.15) K while refractive indexes were determined within temperature range of (288.15{\^a}??333.15) K. Among the investigated novel ILs, bnthiaAMPS showed the highest viscosity and density over the entire temperature range and an enhanced CO2 dissolution of 0.65 mol fraction was observed at 1 MPa and 298.15 K. Furthermore, the Henry's constant of bnthiaAMPS was found to be 1.199 MPa which was 23.7, 32.6, and 56.0\% less than diMeimAMPS, diMeimiAMPS and mrphAMPS, respectively. The present study provides a detailed insight to understand structure-activity relation between physicochemical properties and CO2 solubility of studied ILs. {\^A}{\copyright} 2019 Elsevier B.V.}, author = {Sardar, S. and Mumtaz, A. and Yasinzai, M. and Wilfred, C. D.}, issn = {01677322} }